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Research Project
Mechanical Engineering and Resource Sustainability Center
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Publications
Experimental Investigation of Green Nanofluids: Assessment of Wettability, Viscosity and Thermal Conductivity
Publication . Nobrega, Glauco Tapijara Vallicelli; Cardoso, Beatriz D.; Barbosa, Filipe; Pinho, Diana; Abreu, Cristiano; Souza, Reinaldo Rodrigues de; Moita, Ana S.; Ribeiro, J.E.; Lima, Rui A.
Metallic nanoparticles are a type of nanomaterial
synthesized from metallic precursors. Due to their unique
physiochemical, electrical, and optical properties, metallic
nanoparticles are widely studied and applied in various areas
such as medicine, electronics, and heat transfer systems.
However, conventional synthesis methods to produce metallic
nanoparticles face challenges such as instability and
environmental concerns, prompting the exploration of greener
synthesis methods. Green synthesis uses natural resources like
plants and algae as reducing agents, offering a more
environmentally friendly approach for the synthesis of metallic
nanoparticles. These green-synthesized metallic nanoparticles
can enhance heat transfer by becoming part of nanofluids (NFs),
which are colloidal mixtures of NPs in a fluid base. NFs,
employed for heat transfer. As a result, it is essential to
characterize the NFs regarding wettability, viscosity, and
thermal conductivity. The results of the spectrophotometer
confirmed the green synthesis of NPs, and it was observed that
the increase in NP concentration impacted the contact angle,
improving the ability to wet. The thermal conductivity is also
modified, with an improvement of 11.3% compared to distilled
water, without a significant increase in fluid viscosity.
Composite material of PDMS with interchangeable transmittance: study of optical, mechanical properties and wettability
Publication . Sales, Flaminio; Souza, Andrews; Ariati, Ronaldo; Noronha, Verônica Teixeira; Giovanetti, Elder Gulick; Lima, Rui A.; Ribeiro, J.E.
Polydimethylsiloxane (PDMS) is a polymer that has attracted the attention of researchers due to its unique properties such as transparency, biocompatibility, high flexibility, and physical and chemical stability. In addition, PDMS modification and combination with other materials can expand its range of applications. For instance, the ability to perform superhydrophobic coating allows for the manufacture of lenses. However, many of these processes are complex and expensive. One of the most promising modifications, which consists of the development of an interchangeable coating, capable of changing its optical characteristics according to some stimuli, has been underexplored. Thus, we report an experimental study of the mechanical and optical properties and wettability of pure PDMS and of two PDMS composites with the addition of 1% paraffin or beeswax using a gravity casting process. The composites’ tensile strength and hardness were lower when compared with pure PDMS. However, the contact angle was increased, reaching the highest values when using the paraffin additive. Additionally, these composites have shown interesting results for the spectrophotometry tests, i.e., the material changed its optical characteristics when heated, going from opaque at room temperature to transparent, with transmittance around 75%, at 70 °C. As a result, these materials have great potential for use in smart devices, such as sensors, due to its ability to change its transparency at high temperatures.
Low-cost multifunctional vacuum chamber for manufacturing PDMS based composites
Publication . Ariati, Ronaldo; Sales, Flaminio C.P.; Noronha, Verônica Teixeira; Lima, Rui A.; Ribeiro, J.E.
Polydimethylsiloxane (PDMS) is one of the best known elastomers and has been used in
several areas of activity, due to its excellent characteristics and properties, such as biocompatibility,
flexibility, optical transparency and chemical stability. Furthermore, PDMS modified with other
materials promotes the desired changes to broaden its range of applications in various fields of
science. However, the heating, mixing and degassing steps of the manufacturing process have
not received much attention in recent years when it comes to blending with solid materials. For
instance, PDMS has been extensively studied in combination with waxes, which are frequently in
a solid state at room temperature and as a result the interaction and manufacturing process are
extremely complex and can compromise the desired material. Thus, in this work it is proposed a
multifunctional vacuum chamber (MVC) with the aim to improve and accelerate the manufacturing
process of PDMS composites combined with additives, blends and different kinds of solid materials.
The MVC developed in this work allows to control the mixing speed parameters, temperature control
and internal pressure. In addition, it is a low cost equipment and can be used for other possible
modifications with different materials and processes with the ability to control those parameters. As
a result, samples fabricated by using the MVC can achieve a time improvement over 133% at the
heating and mixing step and approximately 200% at the last degassing step. Regarding the complete
manufacturing process, it is possible to achieve an improvement over 150%, when compared with
the conventional manufacturing process. When compared to maximum tensile strength, specimens
manufactured using the MVC have shown a 39% and 65% improvement in maximum strain. The
samples have also shown a 9% improvement in transparency at room temperature and 12% at
a temperature of about 75 C. It should be noted that the proposed MVC can be used for other
blends and manufacturing processes where it is desirable to control the temperature, agitation speed
and pressure.
Additive manufacturing techniques for the fabrication of intracranial aneurysm biomodels
Publication . Rodrigues, D.; Souza, A.; Souza, Maria Sabrina; Ferrera, Conrado; Ribeiro, J.E.; Lima, Rui A.
The hemodynamics of intracranial aneurysm (IA) involves complex phenomena that
influence its growth and rupture. The advancement of additive manufacturing techniques
allowed the development of biomodels suitable for in vitro experimental tests. Thus, we
present in this work the process of manufacturing flow biomodels, using different additive
manufacturing techniques and materials. The biomodels obtained through these methods
proved to be suitable for experiments using imaging techniques and for the validation of
numerical studies.
A Review of Novel Heat Transfer Materials and Fluids for Aerospace Applications
Publication . Nobrega, Glauco Tapijara Vallicelli; Cardoso, Beatriz D.; Souza, Reinaldo Rodrigues de; Pereira, José Eduardo; Pontes, Pedro; Catarino, Susana O.; Pinho, Diana M.D; Lima, Rui A.; Moita, Ana S.
The issue of thermal control for space missions has been critical since the early space missions in the late 1950s. The demands in such environments are heightened, characterized by significant temperature variations and the need to manage substantial densities of heat. The current work offers a comprehensive survey of the innovative materials and thermal fluids employed in the aerospace technological area. In this scope, the materials should exhibit enhanced reliability for facing maintenance and raw materials scarcity. The improved thermophysical properties of the nanofluids increase the efficiency of the systems, allowing the mass/volume reduction in satellites, rovers, and spacecraft. Herein are summarized the main findings from a literature review of more than one hundred works on aerospace thermal management. In this sense, relevant issues in aerospace convection cooling were reported and discussed, using heat pipes and heat exchangers, and with heat transfer ability at high velocity, low pressure, and microgravity. Among the main findings, it could be highlighted the fact that these novel materials and fluids provide enhanced thermal conductivity, stability, and insulation, enhancing the heat transfer capability and preventing the malfunctioning, overheating, and degradation over time of the systems. The resulting indicators will contribute to strategic mapping knowledge and further competence. Also, this work will identify the main scientific and technological gaps and possible challenges for integrating the materials and fluids into existing systems and for maturation and large-scale feasibility for aerospace valorization and technology transfer enhancement.
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Funding agency
Fundação para a Ciência e a Tecnologia
Funding programme
6817 - DCRRNI ID
Funding Award Number
UIDB/04077/2020