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Determination of 2,4,6-trichloroanisole by cyclic voltammetry

dc.contributor.authorFreitas, Patrícia
dc.contributor.authorDias, L.G.
dc.contributor.authorPeres, António M.
dc.contributor.authorCastro, Luís M.
dc.contributor.authorVeloso, Ana C.A.
dc.date.accessioned2014-09-25T16:12:27Z
dc.date.available2014-09-25T16:12:27Z
dc.date.issued2012
dc.description.abstractThe electrochemical reduction of 2,4,6-trichloroanisole (TCA), which is a chlorinated arene with electron-donating substituents, was evaluated by cyclic voltammetry (CV). TCA is a major concern for the winery industry since it is related with “cork taint”, a wine defect. The results obtained in this work showed that CV could be used to detect and quantify TCA in preparative standard solutions. Linear relationships could be set between the current amplitude and TCA concentration (R > 0.999), being the detection (LOD) and quantification (LOQ) limits of 0.8 and 2.0 ppm, respectively. Although, these preliminary limits are higher than the human sensory threshold (around 5 ppt in wine), the simplicity and low-cost of the methodology confer this study a possible role in the development of more efficient, less expensive processes for TCA detection in the industry.por
dc.identifier.citationFreitas, Patrícia; Dias, Luís G.; Peres, António M.; Castro, Luís M.; Veloso, Ana C.A. (2012). Determination of 2,4,6-trichloroanisole by cyclic voltammetry. In 26th European Conference on Solid-State Transducers, Eurosensor 2012. Kraków, Polandpor
dc.identifier.urihttp://hdl.handle.net/10198/10607
dc.language.isoengpor
dc.peerreviewedyespor
dc.titleDetermination of 2,4,6-trichloroanisole by cyclic voltammetrypor
dc.typeconference object
dspace.entity.typePublication
oaire.citation.conferencePlaceKraków, Polandpor
oaire.citation.titleThe 26th European Conference on Solid-State Transducers, Eurosensors 2012por
person.familyNameDias
person.familyNamePeres
person.givenNameLuís G.
person.givenNameAntónio M.
person.identifier107333
person.identifier.ciencia-id2F11-9092-FAAF
person.identifier.ciencia-idCF16-5443-F420
person.identifier.orcid0000-0002-1210-4259
person.identifier.orcid0000-0001-6595-9165
person.identifier.ridI-8470-2012
person.identifier.scopus-author-id23569169900
person.identifier.scopus-author-id7102331969
rcaap.rightsopenAccesspor
rcaap.typeconferenceObjectpor
relation.isAuthorOfPublicationeac8c166-4056-4ed0-8d8d-7ecb2c4481a5
relation.isAuthorOfPublication7d93be47-8dc4-4413-9304-5b978773d3bb
relation.isAuthorOfPublication.latestForDiscoveryeac8c166-4056-4ed0-8d8d-7ecb2c4481a5

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