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Extensive characterization of choline chloride and its solid–liquid equilibrium with water

2022Journal article Open access
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dc.contributor.authorFerreira, Ana I.M.C. Lobo
dc.contributor.authorVilas-Boas, Sérgio M.
dc.contributor.authorSilva, Rodrigo M.A.
dc.contributor.authorMartins, Mónia A.R.
dc.contributor.authorAbranches, Dinis O.
dc.contributor.authorPaz, Filipe A. Almeida
dc.contributor.authorFerreira, Olga
dc.contributor.authorPinho, Simão
dc.contributor.authorSantos, Luís M.N.B.F.
dc.contributor.authorCoutinho, João A.P.
dc.date.accessioned2018-02-19T10:00:00Z
dc.date.accessioned2020-06-22T10:18:21Z
dc.date.available2018-01-19T10:00:00Z
dc.date.available2020-06-22T10:18:21Z
dc.date.issued2022
dc.description.abstractThe importance of choline chloride (ChCl) is recognized due to its widespread use in the formulation of deep eutectic solvents. The controlled addition of water in deep eutectic solvents has been proposed to overcome some of the major drawbacks of these solvents, namely their high hygroscopicities and viscosities. Recently, aqueous solutions of ChCl at specific mole ratios have been presented as a novel, low viscous deep eutectic solvent. Nevertheless, these proposals are suggested without any information about the solid–liquid phase diagram of this system or the deviations from the thermodynamic ideality of its precursors. This work contributes significantly to this matter as the phase behavior of pure ChCl and (ChCl + H2 O) binary mixtures was investigated by calorimetric and analytical techniques. The thermal behavior and stability of ChCl were studied by polarized light optical microscopy and differential scanning calorimetry, confirming the existence of a solid–solid transition at 352.2 0.6 K. Additionally, heat capacity measurements of pure ChCl (covering both ChCl solid phases) and aqueous solutions of ChCl (xChCl o 0.4) were performed using a heat-flow differential scanning microcalorimeter or a high- precision heat capacity drop calorimeter, allowing the estimation of a heat capacity change of (ChCl) E 39.3 10 J K 1 mol 1 , between the hypothetical liquid and the observed crystalline phase at 298.15 K. The solid–liquid phase diagram of the ChCl + water mixture was investigated in the whole concentration range by differential scanning calorimetry and the analytical shake-flask method. The phase diagram obtained for the mixture shows an eutectic temperature of 204 K, at a mole fraction of choline chloride close to xChCl = 0.2, and a shift of the solid–solid transition of ChCl–water mixtures of 10 K below the value observed for pure choline chloride, suggesting the appearance of a new crystalline structure of ChCl in the presence of water, as confirmed by X-ray diffraction. The liquid phase presents significant negative deviations to ideality for water while COSMO-RS predicts a near ideal behaviour for ChCl.
dc.description.sponsorshipThis work was supported by the Fundação para a Ciência e Tecnologia (FCT) (funded by national funds through the FCT/ MCTES (PIDDAC)) to CIQUP, the Faculty of Science, University of Porto (Project UIDB/00081/2020), the IMS-Institute of Mole- cular Sciences (LA/P/0056/2020), the CIMO-Mountain Research Center (Project UIDB/00690/2020), and the CICECO-Aveiro Institute of Materials (Projects UIDB/50011/2020, UIDP/50011/ 2020 and LA/P/0006/2020). Support was also provided by project AllNat—POCI-01-0145-FEDER-030463 (PTDC/EQU-EPQ/30463/ 2017), funded by FEDER funds through COMPETE2020---Prog. Operacional Competitividade e Internacionalizaça ̃o (POCI), and by national funds through the Foundation for Science and Technology (FCT/MCTES). The NMR spectrometers are a part of the National NMR Network (PTNMR) and are partially supported by the Infrastructure Project No. 022161 (co- financed by FEDER through COMPETE 2020, POCI and PORL and FCT through PIDDAC). AIMCLF is also financed by national funds through the FCT-I.P., in the framework of the execution of the program contract provided in paragraphs 4, 5 and 6 of art. 23 of Law no. 57/2016 of 29 August, as amended by Law no. 57/2017 of 19 July. Se ́rgio M. Vilas-Boas acknowledges the FCT and European Social Fund (ESF) for his PhD grant (SFRH/BD/138149/2018).
dc.description.versioninfo:eu-repo/semantics/publishedVersionen_EN
dc.identifier.citationFerreira, Ana I.M.C. Lobo; Vilas-Boas, Sérgio M.; Silva, Rodrigo M.A.; Martins, Mónia A.R.; Abranches, Dinis O.; Paz, Filipe A. Almeida; Ferreira, Olga; Pinho, Simão; Santos, Luís M.N.B.F.; Coutinho, João A.P. (2022). Extensive characterization of choline chloride and its solid–liquid equilibrium with water. Physical Chemistry Chemical Physics. ISSN 1463-9076. 24, p. 14886–14897en_EN
dc.identifier.doi10.1039/d2cp00377een_EN
dc.identifier.eissn1463-9084
dc.identifier.issn1463-9076
dc.identifier.urihttp://hdl.handle.net/10198/22292
dc.language.isoeng
dc.peerreviewedyesen_EN
dc.publisherRoyal Society of Chemistry
dc.relationLA/P/0056/2020
dc.relationChemistry Research Unit of University of Porto
dc.relationMountain Research Center
dc.relationCICECO-Aveiro Institute of Materials
dc.relationCICECO-Aveiro Institute of Materials
dc.relationNovos Processos de Separação para o Fracionamento e Purificação de Terpenos
dc.subjectCholine chlorideen_EN
dc.titleExtensive characterization of choline chloride and its solid–liquid equilibrium with wateren_EN
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleChemistry Research Unit of University of Porto
oaire.awardTitleMountain Research Center
oaire.awardTitleCICECO-Aveiro Institute of Materials
oaire.awardTitleCICECO-Aveiro Institute of Materials
oaire.awardTitleNovos Processos de Separação para o Fracionamento e Purificação de Terpenos
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00081%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50011%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50011%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/9471 - RIDTI/PTDC%2FEQU-EPQ%2F30463%2F2017/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT//SFRH%2FBD%2F138149%2F2018/PT
oaire.citation.titlePhysical Chemistry Chemical Physics
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream9471 - RIDTI
person.familyNameFerreira
person.familyNamePinho
person.givenNameOlga
person.givenNameSimão
person.identifier810882
person.identifier.ciencia-id9F1D-C75A-4A54
person.identifier.ciencia-id481D-73AD-8D0F
person.identifier.orcid0000-0001-8414-3479
person.identifier.orcid0000-0002-9211-857X
person.identifier.ridM-4567-2013
person.identifier.ridD-4148-2013
person.identifier.scopus-author-id57203083219
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project.funder.identifierhttp://doi.org/10.13039/501100001871
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project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
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rcaap.rightsopenAccessen_EN
rcaap.typearticleen_EN
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