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Biogas upgrading using shaped MOF MIL-160(Al) by pressure swing adsorption process: Experimental and dynamic modelling assessment

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dc.contributor.authorKarimi, Mohsen
dc.contributor.authorSiqueira, Rafael M.
dc.contributor.authorRodrigues, Alírio
dc.contributor.authorNouar, Farid
dc.contributor.authorSilva, José A.C.
dc.contributor.authorSerre, Christian
dc.contributor.authorFerreira, Alexandre
dc.date.accessioned2024-06-13T11:13:42Z
dc.date.available2024-06-13T11:13:42Z
dc.date.issued2024
dc.description.abstractBiogas has been introduced as a sustainable source of energy, which is considered as a promising alternative for conventional fossil fuels. Indeed, biogas requires to be upgraded from the impurities, specifically, carbon dioxide to be commercially utilized. In this study, the potential of shaped form MIL-160(Al) as a water stable Al dicarboxylate microporous MOF has been assessed concerning the biogas upgrading application. To this end, firstly, the dynamic fixed-bed adsorption of carbon dioxide and methane was investigated at 313 K and 4.0 bar. The measured breakthrough outcomes were simulated with a developed mathematical model, which the results confirmed an acceptable potential of model predictions. Afterwards, a pressure swing adsorption (PSA) process with 5-steps was designed relying on dynamic equilibrium results, and experimentally validated by a lab-scale PSA set-up for a 50:50 CO2/CH4 mixture. Finally, an industrial PSA process was designed to have a precise knowledge on the potential of MIL-160(Al) for biogas upgrading for large scale applications. The results demonstrated the purity and recovery of methane around 99 % and 63 %, respectively, which indicated the appealing capacity of this adsorbent for such a purpose.pt_PT
dc.description.sponsorshipThis work was financially supported by LA/P/0045/2020 (ALiCE), UIDB/50020/2020, and UIDP/50020/2020 (LSRE-LCM), funded by national funds through FCT/MCTES (PIDDAC). It also received financial support by national funds through FCT/MCTES (PIDDAC): CIMO, UIDB/ 00690/2020 (DOI: 10.54499/UIDB/00690/2020) and UIDP/00690/ 2020 (DOI: 10.54499/UIDP/00690/2020); and SusTEC, LA/P/0007/ 2020 (DOI: 10.54499/LA/P/0007/2020). Authors also acknowledge Kyung-Ho Cho and U-Hwang Lee from Korea Research Institute of Chemical Technology (KRICT), Republic of Korea, for their contributions in the shaping MIL-160(Al). M. Karimi acknowledges research grants awarded by Foundation of Science and Technology of Portugal (FCT) under SFRH/BD/140550/2018 project and University of Porto under FEUP-BioGasUpGMIL160 project.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationKarimi, Mohsen; Siqueira, Rafael M.; Rodrigues, Alírio E.; Nouar, Farid; Silva, José A.C.; Serre, Christian; Ferreira, Alexandre (2024). Biogas upgrading using shaped MOF MIL-160(Al) by pressure swing adsorption process: Experimental and dynamic modelling assessment. Separation and Purification Technology. ISSN 1383-5866. 344, p. 1-13pt_PT
dc.identifier.doi10.1016/j.seppur.2024.127260pt_PT
dc.identifier.issn1383-5866
dc.identifier.urihttp://hdl.handle.net/10198/29897
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationALICE - Associate Laboratory in Chemical Engineering
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationMountain Research Center
dc.relationMountain Research Center
dc.relationAssociate Laboratory for Sustainability and Tecnology in Mountain Regions
dc.relationProcess Development for Carbon Dioxide Adsorption by Metal Organic Frameworks MOFs - Applications for Clean Energy and Environmental Protection
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectAdsorptionpt_PT
dc.subjectBiogas upgradingpt_PT
dc.subjectMOF MIL-160(Al)pt_PT
dc.subjectPSA processpt_PT
dc.subjectSustainabilitypt_PT
dc.titleBiogas upgrading using shaped MOF MIL-160(Al) by pressure swing adsorption process: Experimental and dynamic modelling assessmentpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleALICE - Associate Laboratory in Chemical Engineering
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleMountain Research Center
oaire.awardTitleMountain Research Center
oaire.awardTitleAssociate Laboratory for Sustainability and Tecnology in Mountain Regions
oaire.awardTitleProcess Development for Carbon Dioxide Adsorption by Metal Organic Frameworks MOFs - Applications for Clean Energy and Environmental Protection
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0045%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50020%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50020%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0007%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/POR_NORTE/SFRH%2FBD%2F140550%2F2018/PT
oaire.citation.endPage13pt_PT
oaire.citation.startPage1pt_PT
oaire.citation.titleSeparation and Purification Technologypt_PT
oaire.citation.volume344pt_PT
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
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oaire.fundingStreamPOR_NORTE
person.familyNameSilva
person.givenNameJosé A.C.
person.identifier.ciencia-idC11B-F5CF-7C78
person.identifier.orcid0000-0003-1778-3833
person.identifier.scopus-author-id7403023684
project.funder.identifierhttp://doi.org/10.13039/501100001871
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project.funder.nameFundação para a Ciência e a Tecnologia
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project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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