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Green hydrogen recovery from natural gas grids by adsorption process

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Abstract(s)

In this work, the binder-free zeolite 13X was tested to purify green hydrogen injected into natural gas grids. Green hydrogen can be a key factor in meeting global energy demand while contributing to climate goals. In this way, breakthrough curve experiments were performed to assess the equilibrium and kinetic adsorption for H2 and CH4 in binder- free zeolite 13X. This work covers the lack of adsorption data and multicomponent breakthrough curves of H2/CH4 at low temperatures (until 195 K) which were not available in the literature. The equilibrium data were modeled by using the dual-site Langmuir isotherm model and the multicomponent breakthrough curves were simulated using a mathematical model implemented in MATLAB. Performance parameters based on equilibrium data were discussed. Overall, binder-free zeolite 13X has great potential to separate H2 from CH4 based on equilibrium (higher capacity for CH4 with fast diffusion of both gases).

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Keywords

Green Hydrogen Hydrogen Recovery Hydrogen Purification Natural Gas Grids Zeolite 13X Process Simulation

Pedagogical Context

Citation

Zafanelli, Lucas F.A.S.; Aly, Ezzeldin; Henrique, Adriano; Rodrigues, Alírio E.; Silva, José A.C. (2023). Green hydrogen recovery from natural gas grids by adsorption process. In Ana Maria Alves Queiroz da Silva; António Manuel Coelho Lino Peres; António Manuel Esteves Ribeiro; Maria Olga de Amorim e Sá Ferreira; Maria Filomena Filipe Barreiro; Paulo Miguel Pereira de Brito; Simão Pedro de Almeida Pinho (Eds.) 14th International Chemical and Biological Engineering Conference (CHEMPOR 2023): book of Abstracts. Bragança. ISBN 978-972-745-327-6

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Instituto Politécnico de Bragança

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