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Separation of CO2/N2 onto Shaped MOF MIL-160(Al) Using the Pressure Swing Adsorption Process for Post-combustion Application

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dc.contributor.authorKarimi, Mohsen
dc.contributor.authorSiqueira, Rafael M.
dc.contributor.authorRodrigues, Alírio
dc.contributor.authorNouar, Farid
dc.contributor.authorSilva, José A.C.
dc.contributor.authorSerre, Christian
dc.contributor.authorFerreira, Alexandre F.P.
dc.date.accessioned2024-06-05T16:28:47Z
dc.date.available2024-06-05T16:28:47Z
dc.date.issued2024
dc.description.abstractAdsorption processes have already been considered as an appealing technology for carbon capture and climate change mitigation. Accordingly, this work investigated the capacity of shaped MIL-160(Al) as a water stable bioderived Al dicarboxylate microporous metal-organic framework for separation of carbon dioxide and nitrogen concerning postcombustion application. First, breakthrough experiments of carbon dioxide and nitrogen were accomplished at 313 K and 4.0 bar. Then, a set of equations/relations were considered to model the dynamic fixed-bed tests, in which the outcomes proved the capacity of the developed model for such a purpose. Next, a pressure swing adsorption (PSA) process with five steps, including pressurization, feed, rinse, blowdown, and purge, was planned and validated using performed experiments in a laboratory-scale PSA setup. In the end, an industrial PSA process was designed to attain a better grasp of the capacity of MIL-160(Al) for postcombustion application. The results indicated an exciting potential of this adsorbent for postcombustion carbon capture, with the purity and recovery of carbon dioxide around 67.3 and 99.1%, respectively.pt_PT
dc.description.sponsorshipThis work was financially supported by LA/P/0045/2020 (ALiCE), UIDB/50020/2020, and UIDP/50020/2020 (LSRE-LCM), funded by national funds through FCT/ MCTES (PIDDAC). It also received financial support by national funds through FCT/MCTES (PIDDAC): CIMO, UIDB/00690/2020 (DOI: 10.54499/UIDB/00690/2020) and UIDP/00690/2020 (DOI: 10.54499/UIDP/00690/2020), and SusTEC, LA/P/0007/2020 (DOI: 10.54499/LA/P/0007/2020). The authors also acknowledge Kyung-Ho Cho and U-Hwang Lee from the Korea Research Institute of Chemical Technology (KRICT), Republic of Korea, for their contributions in the shaping MIL-160(Al). M.K. acknowledges research grants awarded by the Foundation of Science and Technology of Portugal (FCT) under SFRH/BD/140550/2018 project and the University of Porto under FEUPBioGasUpGMIL160 project.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationKarimi, Mohsen; Siqueira, Rafael M.; Rodrigues, Alírio E.; Nouar, Farid; Silva, José A.C.; Serre, Christian; Ferreira, Alexandre F.P. (2024). Separation of CO2/N2 onto Shaped MOF MIL-160(Al) Using the Pressure Swing Adsorption Process for Post-combustion Application. Industrial & Engineering Chemistry Research. ISSN 0888-5885. 63:19, p. 8772-8785pt_PT
dc.identifier.doi10.1021/acs.iecr.4c00611pt_PT
dc.identifier.eissn1520-5045
dc.identifier.issn0888-5885
dc.identifier.urihttp://hdl.handle.net/10198/29869
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherAmerican Chemical Societypt_PT
dc.relationALICE - Associate Laboratory in Chemical Engineering
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationMountain Research Center
dc.relationMountain Research Center
dc.relationAssociate Laboratory for Sustainability and Tecnology in Mountain Regions
dc.relationProcess Development for Carbon Dioxide Adsorption by Metal Organic Frameworks MOFs - Applications for Clean Energy and Environmental Protection
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectMetal-organic frameworkspt_PT
dc.subjectCO2 capturept_PT
dc.titleSeparation of CO2/N2 onto Shaped MOF MIL-160(Al) Using the Pressure Swing Adsorption Process for Post-combustion Applicationpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleALICE - Associate Laboratory in Chemical Engineering
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleMountain Research Center
oaire.awardTitleMountain Research Center
oaire.awardTitleAssociate Laboratory for Sustainability and Tecnology in Mountain Regions
oaire.awardTitleProcess Development for Carbon Dioxide Adsorption by Metal Organic Frameworks MOFs - Applications for Clean Energy and Environmental Protection
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0045%2F2020/PT
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oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50020%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0007%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/POR_NORTE/SFRH%2FBD%2F140550%2F2018/PT
oaire.citation.endPage8785pt_PT
oaire.citation.issue19pt_PT
oaire.citation.startPage8772pt_PT
oaire.citation.titleIndustrial & Engineering Chemistry Researchpt_PT
oaire.citation.volume63pt_PT
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
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oaire.fundingStreamPOR_NORTE
person.familyNameSilva
person.givenNameJosé A.C.
person.identifier.ciencia-idC11B-F5CF-7C78
person.identifier.orcid0000-0003-1778-3833
person.identifier.scopus-author-id7403023684
project.funder.identifierhttp://doi.org/10.13039/501100001871
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project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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