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Separation of CO2/N2 onto Shaped MOF MIL-160(Al) Using the Pressure Swing Adsorption Process for Post-combustion Application

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dc.contributor.authorKarimi, Mohsen
dc.contributor.authorSiqueira, Rafael M.
dc.contributor.authorRodrigues, Alírio
dc.contributor.authorNouar, Farid
dc.contributor.authorSilva, José A.C.
dc.contributor.authorSerre, Christian
dc.contributor.authorFerreira, Alexandre F.P.
dc.date.accessioned2024-06-05T16:28:47Z
dc.date.available2024-06-05T16:28:47Z
dc.date.issued2024
dc.description.abstractAdsorption processes have already been considered as an appealing technology for carbon capture and climate change mitigation. Accordingly, this work investigated the capacity of shaped MIL-160(Al) as a water stable bioderived Al dicarboxylate microporous metal-organic framework for separation of carbon dioxide and nitrogen concerning postcombustion application. First, breakthrough experiments of carbon dioxide and nitrogen were accomplished at 313 K and 4.0 bar. Then, a set of equations/relations were considered to model the dynamic fixed-bed tests, in which the outcomes proved the capacity of the developed model for such a purpose. Next, a pressure swing adsorption (PSA) process with five steps, including pressurization, feed, rinse, blowdown, and purge, was planned and validated using performed experiments in a laboratory-scale PSA setup. In the end, an industrial PSA process was designed to attain a better grasp of the capacity of MIL-160(Al) for postcombustion application. The results indicated an exciting potential of this adsorbent for postcombustion carbon capture, with the purity and recovery of carbon dioxide around 67.3 and 99.1%, respectively.pt_PT
dc.description.sponsorshipThis work was financially supported by LA/P/0045/2020 (ALiCE), UIDB/50020/2020, and UIDP/50020/2020 (LSRE-LCM), funded by national funds through FCT/ MCTES (PIDDAC). It also received financial support by national funds through FCT/MCTES (PIDDAC): CIMO, UIDB/00690/2020 (DOI: 10.54499/UIDB/00690/2020) and UIDP/00690/2020 (DOI: 10.54499/UIDP/00690/2020), and SusTEC, LA/P/0007/2020 (DOI: 10.54499/LA/P/0007/2020). The authors also acknowledge Kyung-Ho Cho and U-Hwang Lee from the Korea Research Institute of Chemical Technology (KRICT), Republic of Korea, for their contributions in the shaping MIL-160(Al). M.K. acknowledges research grants awarded by the Foundation of Science and Technology of Portugal (FCT) under SFRH/BD/140550/2018 project and the University of Porto under FEUPBioGasUpGMIL160 project.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationKarimi, Mohsen; Siqueira, Rafael M.; Rodrigues, Alírio E.; Nouar, Farid; Silva, José A.C.; Serre, Christian; Ferreira, Alexandre F.P. (2024). Separation of CO2/N2 onto Shaped MOF MIL-160(Al) Using the Pressure Swing Adsorption Process for Post-combustion Application. Industrial & Engineering Chemistry Research. ISSN 0888-5885. 63:19, p. 8772-8785pt_PT
dc.identifier.doi10.1021/acs.iecr.4c00611pt_PT
dc.identifier.eissn1520-5045
dc.identifier.issn0888-5885
dc.identifier.urihttp://hdl.handle.net/10198/29869
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherAmerican Chemical Societypt_PT
dc.relationALICE - Associate Laboratory in Chemical Engineering
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationMountain Research Center - UIDB/00690/2020
dc.relationMountain Research Center - UIDP/00690/2020
dc.relationAssociate Laboratory for Sustainability and Tecnology in Mountain Regions - LA/P/0007/2020
dc.relationProcess Development for Carbon Dioxide Adsorption by Metal Organic Frameworks MOFs - Applications for Clean Energy and Environmental Protection
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectMetal-organic frameworkspt_PT
dc.subjectCO2 capturept_PT
dc.titleSeparation of CO2/N2 onto Shaped MOF MIL-160(Al) Using the Pressure Swing Adsorption Process for Post-combustion Applicationpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardNumberLA/P/0045/2020
oaire.awardNumberUIDB/50020/2020
oaire.awardNumberUIDP/50020/2020
oaire.awardNumberUIDB/00690/2020
oaire.awardNumberUIDP/00690/2020
oaire.awardNumberLA/P/0007/2020
oaire.awardNumberSFRH/BD/140550/2018
oaire.awardTitleALICE - Associate Laboratory in Chemical Engineering
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleMountain Research Center - UIDB/00690/2020
oaire.awardTitleMountain Research Center - UIDP/00690/2020
oaire.awardTitleAssociate Laboratory for Sustainability and Tecnology in Mountain Regions - LA/P/0007/2020
oaire.awardTitleProcess Development for Carbon Dioxide Adsorption by Metal Organic Frameworks MOFs - Applications for Clean Energy and Environmental Protection
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0045%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50020%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50020%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0007%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/POR_NORTE/SFRH%2FBD%2F140550%2F2018/PT
oaire.citation.endPage8785pt_PT
oaire.citation.issue19pt_PT
oaire.citation.startPage8772pt_PT
oaire.citation.titleIndustrial & Engineering Chemistry Researchpt_PT
oaire.citation.volume63pt_PT
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStreamPOR_NORTE
person.familyNameSilva
person.givenNameJosé A.C.
person.identifier.ciencia-idC11B-F5CF-7C78
person.identifier.orcid0000-0003-1778-3833
person.identifier.scopus-author-id7403023684
project.funder.identifierhttp://doi.org/10.13039/501100001871
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project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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