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INSTITUTE OF EARTH SCIENCES

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Publications

Analysis of the urban heat island in Bragança, Portugal, using MODIS data (2003-2022)
Publication . Almeida, Cátia Rodrigues de; Alirio, João; Gonçalves, Artur; Teodoro, Ana Cláudia
Urban Heat Island (UHI) is an effect that corroborates to the increase of temperature in urban settlements when compared to the surrounding vegetated areas, especially after sunset. This research aimed to understand the Surface Urban Heat Island (SUHI), a sub-classification correlated to the UHI effect, in the city of Bragança (Portugal), at 23 points classified in different Local Climate Zone (LCZ), between 2003 and 2022, using Remote Sensing (RS) data from the Moderate Resolution Imaging Spectroradiometer (MODIS) sensor. The data were obtained at four passage times: 11am, 1pm, 10pm and 2am and analysed separately for summer and winter. Qualitative and quantitative analyses were applied, using an average of 1,337 Land Surface Temperature (LST) data, processed in the Google Earth Engine (GEE) platform. The computation of the SUHI intensity (SUHIint) for each year was obtained from the differences in LST between each of the LCZ and the average values from Rural Areas (RCD), considering both summer and winter campaigns. The boxplots showed similar medians in all LCZs at 11am and 1pm. At 10pm and 2am, only slight differences were found among the median values. The similarity in results may be associated with the low spatial resolution of the sensor and the difficulty in distinguishing between LCZs. The SUHIint was positive in most of the results (about 71%). Of the 23 points analysed, ten were not located in unique pixels, which compromised the analysis of the results in the different LCZs. This condition reinforces the need for use higher spatial resolution data to allow for a differentiation among LCZs data.
A LCT pegmatite spectral library of the aldeia spodumene deposit: contributes to mineral exploration
Publication . Almeida, Cátia Rodrigues de; Santos, Douglas; Vasques, Julia Tucker; Cardoso-Fernandes, Joana; Lima, Alexandre; Teodoro, Ana Cláudia
Several methodologies can be employed in the prospection of Lithium (Li) in hard-rock (pegmatites). Spectrometry analysis, a Remote Sensing (RS) technique, can be applied to understand the surface spectral response of a sample, both to identify the rock-forming or alteration minerals in its composition and to validate the data collected in situ (by sensors onboard satellites/drones, for example). This paper aims to make available for public use the information acquired on the spectral composition of rock samples from the Barroso pegmatite field in Portugal, within the scope of the INOVMINERAL4.0 project. As a result, a spectral library was created with 47 spectra, collected from 11 different samples. All data is made available in a universal format, thus contributing to open science, corroborating the validation of local spectral data, and stimulating the creation of other databases, in other locations.
Spectral library of European pegmatites, pegmatite minerals and pegmatite host-rocks – the GREENPEG project database
Publication . Cardoso-Fernandes, Joana; Santos, Douglas; Almeida, Cátia Rodrigues de; Lima, Alexandre; Teodoro, Ana Cláudia
The New Exploration Tools for European Pegmatite Green-Tech Resources (GREENPEG) spectral database contains the spectral signature, obtained through reflectance spectroscopy studies, of European pegmatites and minerals as well as their host rocks. Samples include pegmatites of the Nb–Y–F (NYF) and Li–Cs–Ta (LCT) chemical types and host rocks from pegmatite locations in Austria, Ireland, Norway, Portugal, and Spain. The database contains the reflectance spectra (raw and continuum-removed spectra), sample photographs, and main absorption features automatically extracted by a self-proposed Python routine. Whenever possible, spectral mineralogy was interpreted based on the continuum-removed spectra. A detailed description of the database, its content and structure, the measuring instrument, and interoperability with geographic information system (GIS) tools is available in this database report. Moreover, examples of how the data can be used and interpreted are also provided. The advantages and added value of the presented dataset reside in its European scale, with representative samples from pegmatites with distinct genesis, mineralogy, structure, and host rocks that can be used as a reference for pegmatite exploration at a global scale via, for example, satellite image processing. The reported spectral mineral assemblages can also be of interest when considering resource estimation or ore processing. Thus, it is expected that this open dataset, available on the Zenodo platform https://doi.org/10.5281/zenodo.6518318 (Cardoso-Fernandes et al., 2022b), will be a reference for distinct types of users, ranging from academia to industry.
The Development of a Novel Nitrate Portable Measurement System Based on a UV Paired Diode–Photodiode
Publication . Fernandes, Samuel; Tlemçani, Mouhaydine; Bortoli, Daniele; Feliciano, Manuel; Lopes, Maria Elmina
Nitrates can cause severe ecological imbalances in aquatic ecosystems, with considerable consequences for human health. Therefore, monitoring this inorganic form of nitrogen is essential for any water quality management structure. This research was conducted to develop a novel Nitrate Portable Measurement System (NPMS) to monitor nitrate concentrations in water samples. NPMS is a reagent-free ultraviolet system developed using low-cost electronic components. Its operation principle is based on the Beer–Lambert law for measuring nitrate concentrations in water samples through light absorption in the spectral range of 295–315 nm. The system is equipped with a ready-to-use ultraviolet sensor, light emission diode (LED), op-amp, microcontroller, liquid crystal display, quartz cuvette, temperature sensor, and battery. All the components are assembled in a 3D-printed enclosure box, which allows a very compact self-contained equipment with high portability, enabling field and near-real-time measurements. The proposed methodology and the developed instrument were used to analyze multiple nitrate standard solutions. The performance was evaluated in comparison to the Nicolet Evolution 300, a classical UV–Vis spectrophotometer. The results demonstrate a strong correlation between the retrieved measurements by both instruments within the investigated spectral band and for concentrations above 5 mg NO3−/L.
The INOVMineral project’s contribution to mineral exploration - a WebGIS integration and visualization of spectral and geophysical properties of the aldeia lct pegmatite spodumene deposit
Publication . Cardoso-Fernandes, Joana; Santos, Douglas; Almeida, Cátia Rodrigues de; Vasques, Julia Tucker; Mendes, Ariane; Ribeiro, Ricardo; Azzalini, Antonio; Duarte, Lia; Moura, Rui; Lima, Alexandre; Teodoro, Ana Cláudia
Due to the current energetic transition, new geological exploration technologies are needed to discover mineral deposits containing critical materials such as lithium (Li). The vast majority of European Li deposits are related to Li–Cs–Ta (LCT) pegmatites. A review of the literature indicates that conventional exploration campaigns are dominated by geochemical surveys and related exploration tools. However, other exploration techniques must be evaluated, namely, remote sensing (RS) and geophysics. This work presents the results of the INOVMINERAL4.0 project obtained through alternative approaches to traditional geochemistry that were gathered and integrated into a webGIS application. The specific objectives were to: (i) assess the potential of high-resolution elevation data; (ii) evaluate geophysical methods, particularly radiometry; (iii) establish a methodology for spectral data acquisition and build a spectral library; (iv) compare obtained spectra with Landsat 9 data for pegmatite identification; and (v) implement a user-friendly webGIS platform for data integration and visualization. Radiometric data acquisition using geophysical techniques effectively discriminated pegmatites from host rocks. The developed spectral library provides valuable insights for spacebased exploration. Landsat 9 data accurately identified known LCT pegmatite targets compared with Landsat 8. The user-friendly webGIS platform facilitates data integration, visualization, and sharing, supporting potential users in similar exploration approaches.

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Funders

Funding agency

Fundação para a Ciência e a Tecnologia

Funding programme

6817 - DCRRNI ID

Funding Award Number

UIDP/04683/2020

ID