Browsing by Author "Charres, Isabella"
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- Comprehensive assessment of PM10 from home heating using different appliances and biomass fuels: Chemical composition, oxidative potential, and ecotoxicityPublication . Cipoli, Yago Alonso; Vicente, Estela D.; Charres, Isabella; Evtyugina, Margarita; Alfosea-Simón, Marina; Lucarelli, Franco; Kováts, Nora; Ryšavý, Jiří; Feliciano, Manuel; Alves, CéliaThe European Union has implemented policies to promote renewable energy, with an emphasis on biomass for heat generation. However, residential biomass combustion is a major source of particulate matter (PM10), and its chemical constituents pose health concerns worldwide. This study characterised the organic and inorganic composition, oxidative potential (OP), and ecotoxicity of PM10 indoors and outdoors during the operation of two heating appliances fuelled with different types of biomasses: a modern hydronic stove and a traditional wood stove. PM10 concentrations were higher in the room equipped with the traditional system during the combustion of briquettes (95.9 f 74.9 mu g m-3) and firewood (50.1 f 25.6 mu g m- 3), compared to the modern stove using pellets (27.1 f 11.8 mu g m-3) and olive stone (23.0 f 4.5 mu g m- 3). While element oxides accounted for similar PM10 mass fractions (7 %), the wood stove produced higher levels of organic constituents, including carbonaceous fractions, polycyclic aromatic hydrocarbons (PAHs), quinones and saccharides. Significant correlations between OP assays and concentrations of PAHs, quinones and phenolic compounds were found in the room equipped with wood stove, with indoor to outdoor (I/O) ratios higher than 1. In contrast, I/O ratios below 1 were observed for OP in PM10 samples collected during hydronic stove operation. Ecotoxicity assays using Aliivibrio fischeri classified indoor PM10 from the wood stove as 'very toxic', whereas samples from the hydronic stove exhibited lower toxicity and OP levels. These findings highlight the need to reconcile renewable energy goals with air quality and public health.
- School air quality and thermal comfort: a multi-pollutant seasonal assessmentPublication . Charres, Isabella; Furst, Leonardo; Furst, Leonardo; Vicente, Estela D.; Soares, Marlene; Viegas, Carla; Cervantes, Renata; Cerqueira, Mário; Pena, Pedro; Feliciano, Manuel; Alves, CéliaAs evidence of children's vulnerability to air pollution grows, research on school air quality has increased significantly in the 21st century. Given the complex factors influencing indoor and outdoor air quality in schools, each study offers valuable insights. This study contributes by assessing particulate matter, gaseous pollutants, thermal comfort and microorganisms in a large school encompassing different education levels over two seasons. The assessment combined passive and continuous sampling using various techniques, including chromatography and estimations of air change and ventilation rates. Classroom ventilation was insufficient to ensure adequate air renewal. During class hours, CO2 concentrations ranged from 760 to 1,118 ppm in winter and from 807 to 1,022 ppm in spring, repeatedly exceeding 1,000 ppm. CO2 and PM10 concentrations were significantly higher during school hours than when the classrooms were empty, indicating the strong influence of school activities. In contrast, PM1 and PM2.5 concentrations were more influenced by external factors, especially outside of school hours. The lack of thermal comfort created an unhealthy environment. Carbonyl concentrations were higher in classrooms (average: 68.8 mu g m-3) compared to the schoolyard (3.86 mu g m-3), in both seasons. Microbial analysis revealed the presence of fungi with toxigenic potential, with the highest fungal diversity observed in spring. These findings highlight that while some pollutant levels may appear low, they can occasionally reach extremely high levels, even in newer buildings. The novelty of this research lies in demonstrating that, despite recent improvements and numerous studies, significant progress is still needed to ensure healthier school settings.
- Seasonal variation in exposure to particulate matter among children attending different levels of education: comparison of two dosimetry modelsPublication . Charres, Isabella; Cipoli, Yago Alonso; Furst, Leonardo; Vicente, Estela D.; Casotti Rienda, Ismael; Lazaridis, Mihalis; Feliciano, Manuel; Alves, CéliaExposure to particulate matter (PM) has been associated with several adverse health outcomes. Studies indicate that children may be exposed to much higher concentrations of PM at school than in other environments. There exists very little data on the deposited dose of PM while children attend classes. This study was carried out in a school located near an industrial complex in Portugal and attended by children aged 3–12 years. Indoor PM10, PM2.5 and PM1 were measured over two seasons in classrooms representing different school year groups. Particle deposition fractions in the respiratory tract, as well as the deposited doses, were calculated using the Multiple-Path Particle Dosimetry (MPPD) and the Exposure Dose Model (ExDoM2). Both models were implemented assuming an 8-hour exposure scenario to represent the school day. In general, differences in PM concentrations were observed depending on room occupancy periods and season. The highest mean PM2.5 concentration was recorded in winter when the classroom was vacant (23.7 ± 20.5 μg m-3), while the highest mean PM10 level was observed in spring during school hours (61.7 ± 24.2 μg m-3). Regardless of the dosimetry model, the highest deposition of PM10 and PM2.5 was in the upper region, while the lowest was in the tracheobronchial (TB) region. The results indicate that deposited dose and deposition fraction in spring may be more harmful to pupils’ health than in winter. PM10 presented the highest doses, ranging from 54.2 to 128 μg and from 83.9 to 185 μg, according to MPPD and ExDoM2 estimates, respectively.
- Seasonal variations of size-classified aerosol-bound elements in school environments and risk factors for the prevalence of atopic diseases among pupilsPublication . Charres, Isabella; Lucarelli, Franco; Feliciano, Manuel; Furst, Leonardo; Alves, CéliaFive-stage Sioutas impactors were used to collect particulate matter (PM) in 4 classrooms and the playground of a school with various educational levels near the largest industrial chemical complex in Portugal. Monitoring was carried out over a total period of 8 weeks split equally between winter and spring. Samples were analysed for its elemental composition by PIXE. The prevalence of respiratory symptoms in schoolchildren was assessed by applying the International Study of Asthma and Allergies in Childhood (ISAAC) standardised questionnaire. The mass concentration of quasi-ultrafine particles (PM0.25) was higher in winter, but lower than those reported in other studies. Elements accounted for 15.3–17.3 % and 25.6–34.1 % of the total PM10 mass in winter and spring, respectively. Elements such as K, S, Zn, Cu and Br presented a dominant mode in PM0.25, while Al, Mg, Ca, Fe and Si peaked at 2.5 μm. Throughout the campaign, Cl was the main component of the mass of PM greater than 0.5 μm in the schoolyard, while in classrooms Ca constituted the most abundant element of PM2.5-10. The results indicate that soil dust, cleaning products, biomass burning, traffic, the chemical complex and railway affected PM levels at the school. Taking paracetamol and living near roads with intense traffic of heavy vehicles were found to be statistically significant predictors of asthma symptoms, while the frequent consumption of antibiotics and children exposure to parental smoking during the first year of their life were found to increase the odds of developing symptoms of rhinitis.