Publication
Vapor–liquid equilibrium of binary mixtures containing isopropyl acetate and alkanols at 101.32 kPa
| dc.contributor.author | Casimiro, Filipa M. | |
| dc.contributor.author | Constantino, Dânia S.M. | |
| dc.contributor.author | Pereira, Carla S.M. | |
| dc.contributor.author | Ferreira, Olga | |
| dc.contributor.author | Rodrigues, Alírio | |
| dc.contributor.author | Pinho, Simão | |
| dc.date.accessioned | 2016-10-10T15:49:03Z | |
| dc.date.available | 2016-10-10T15:49:03Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | Isobaric vapor-liquid equilibria of binary mixtures of isopropyl acetate plus an alkanol (1-propanol, 2-propanol, 1-butanol, or 2-butanol) were measured at 101.32 kPa, using a dynamic recirculating still. An azeotropic behavior was observed only in the mixtures of isopropyl acetate + 2-propanol and isopropyl acetate + 1-propanol. The application of four thermodynamic consistency tests (the Herington test, the Van Ness test, the infinite dilution test, and the pure component test) showed the high quality of the experimental data. Finally, both NRTL and UNIQUAC activity coefficient models were successfully applied in the correlation of the measured data, with the average absolute deviations in vapor phase composition and temperature of 0.01 and 0.16 K, respectively. | pt_PT |
| dc.identifier.citation | Casimiro, Filipa M.; Constantino, Dânia S. M.; Pereira, Carla S. M.; Ferreira, Olga; Rodrigues, A.E.; Pinho, Simão (2015). Vapor–liquid equilibrium of binary mixtures containing isopropyl acetate and alkanols at 101.32 kPa. Journal of Chemical and Engineering Data. ISSN 0021-9568. 60:11, p.3181-3186 | pt_PT |
| dc.identifier.doi | 10.1021/acs.jced.5b00360 | pt_PT |
| dc.identifier.issn | 0021-9568 | |
| dc.identifier.uri | http://hdl.handle.net/10198/13383 | |
| dc.language.iso | eng | pt_PT |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt_PT |
| dc.subject | Isopropyl acetate | pt_PT |
| dc.subject | Thermodynamic consistency | pt_PT |
| dc.subject | Alcohols | pt_PT |
| dc.subject | Vapour-liquid equilibrium | pt_PT |
| dc.title | Vapor–liquid equilibrium of binary mixtures containing isopropyl acetate and alkanols at 101.32 kPa | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/5876/UID%2FEQU%2F50020%2F2013/PT | |
| oaire.citation.endPage | 3186 | pt_PT |
| oaire.citation.issue | 11 | pt_PT |
| oaire.citation.startPage | 3181 | pt_PT |
| oaire.citation.title | Journal of Chemical and Engineering Data | pt_PT |
| oaire.citation.volume | 60 | pt_PT |
| oaire.fundingStream | 5876 | |
| person.familyName | Ferreira | |
| person.familyName | Pinho | |
| person.givenName | Olga | |
| person.givenName | Simão | |
| person.identifier | 810882 | |
| person.identifier.ciencia-id | 9F1D-C75A-4A54 | |
| person.identifier.ciencia-id | 481D-73AD-8D0F | |
| person.identifier.orcid | 0000-0001-8414-3479 | |
| person.identifier.orcid | 0000-0002-9211-857X | |
| person.identifier.rid | M-4567-2013 | |
| person.identifier.rid | D-4148-2013 | |
| person.identifier.scopus-author-id | 57203083219 | |
| person.identifier.scopus-author-id | 7003570175 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| rcaap.rights | restrictedAccess | pt_PT |
| rcaap.type | article | pt_PT |
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