Publication
Analysis of the synthesis of 1,1-dibutoxyethane in a simulated moving-bed adsorptive reactor
| dc.contributor.author | Graça, Nuno S. | |
| dc.contributor.author | Pais, Luís S. | |
| dc.contributor.author | Silva, Viviana M.T.M. | |
| dc.contributor.author | Rodrigues, Alírio | |
| dc.date.accessioned | 2014-01-14T10:18:05Z | |
| dc.date.available | 2014-01-14T10:18:05Z | |
| dc.date.issued | 2011 | |
| dc.description.abstract | The synthesis of 1,1-dibutoxyethane was carried out in a simulated moving-bed pilot unit LICOSEP 12-26 (Novasep, France) with 12 columns packed with the commercial ion-exchange resin Amberlyst 15(Rohm & Haas, France). Experimentally the best raffinate purity obtained was 85% with a productivity of 5.04 kg L−1 d−1 and a desorbent consumption of 13.5 L kg−1. The TMBR model was used to construct reaction/separation regions and to study the influence of feed composition, switching time, flow rates and mass-transfer resistances on the SMBR performance. The SMBR process shows a potential to be a competitive, efficient and environmentally friendly way to produce 1,1-dibutoxyethane and other acetals. | por |
| dc.identifier.citation | Graça, N.S.; Pais, L.S.; Silva, V.M.T.M.; Rodrigues, A.E. (2011). Analysis of the synthesis of 1,1-dibutoxyethane in a simulated moving-bed adsorptive reactor. Chemical Engineering and Processing. ISSN 0255-2701. 50: 11-12 , p.1214-1225 | por |
| dc.identifier.doi | 10.1016/j.cep.2011.08.004 | |
| dc.identifier.issn | 0255-2701 | |
| dc.identifier.uri | http://hdl.handle.net/10198/9150 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | Elsevier | por |
| dc.subject | 1,1-Dibutoxyethane | por |
| dc.subject | Acetals | por |
| dc.subject | Simulated moving-bed adsorptive reactor | por |
| dc.title | Analysis of the synthesis of 1,1-dibutoxyethane in a simulated moving-bed adsorptive reactor | por |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 1225 | por |
| oaire.citation.startPage | 1214 | por |
| oaire.citation.title | Chemical Engineering and Processing | por |
| oaire.citation.volume | 50 | por |
| person.familyName | Pais | |
| person.givenName | Luís S. | |
| person.identifier.ciencia-id | 421E-0CCD-A84F | |
| person.identifier.orcid | 0000-0002-3000-2862 | |
| person.identifier.scopus-author-id | 6603930478 | |
| rcaap.rights | restrictedAccess | por |
| rcaap.type | article | por |
| relation.isAuthorOfPublication | c6d25534-8487-45b1-90af-d350f4e3ac55 | |
| relation.isAuthorOfPublication.latestForDiscovery | c6d25534-8487-45b1-90af-d350f4e3ac55 |