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Tocopherols content in gluten-free extruded composite flours of rice and different legumes

dc.contributor.authorArribas, Claudia
dc.contributor.authorPereira, Eliana
dc.contributor.authorBarros, Lillian
dc.contributor.authorGuillamón, Eva
dc.contributor.authorFerreira, Isabel C.F.R.
dc.contributor.authorPedrosa, M.M.
dc.date.accessioned2018-02-14T10:07:37Z
dc.date.available2018-02-14T10:07:37Z
dc.date.issued2017
dc.description.abstractExtrusion cooking is a high temperature short time process, which modifies flour properties through starch gelatinization, protein denaturation, complex formation between amylose and lipids, degradation of pigments and improvement of sensory characteristics [1]. Vegetables contain numerous phytochemicals, such as tocopherols, useful for their nutritional and nutraceutical properties. Tocopherols (constituents of vitamin E) appear in several active forms, presenting α-tocopherol the highest biological activity, and being γ-tocopherol the most abundant in vegetable foods, such as sesame seed, soybean, black bean and peanut. Due to its action as a free radical scavenger, vitamin E also plays a role on body protecting against degenerative abnormalities, mainly cancer and cardiovascular diseases [2]. The aim of this study was to evaluate the changes induced by extrusion-cooking on tocopherols content in functional novel formulations of flours containing different proportions of rice (50-80%), bean (20-40%), and carob (5-10%) using the raw materials as control. Tocopherols were determined in the different flours mixtures of ricelegumes by high performance liquid chromatography coupled to a fluorescence detector (HPLC-FL) programmed for excitation at 290 nm and emission at 330 nm, following a procedure previously described by Barros et al. [3]. In general, the samples showed low levels of tocopherols and, in some cases, namely in extrusion samples, the total absence of this vitamin was verified. 𝛼-, γ- and δ- Tocopherols were the vitamers detected in several flours, highlighting bean with the highest concentration of total tocopherols (180 ± 1 μg/100 g). In the samples where tocopherols were detected, the raw materials and in all the evaluated mixtures, γ-tocopherol was the predominant vitamer, being present in greater concentration in bean with values of 172 ± 1 μg/100 g. In this study it was also observed that, after extrusion, a significant reduction occurred in the total tocopherols content, being verified the absence of these molecules in different flour mixtures. In addition, the sensitivity of vitamin E to extrusion cooking depends on the extrusion processing variables and conditions used, particularly extrusion temperatures (that promotes the decrease in α- tocopherol) and moisture during extrusion (decreasing γ-tocopherol content).pt_PT
dc.description.sponsorshipThis work was supported by the Spanish Ministry of Economy and Competitiveness (RTA2012-00042-C02 and RTA2015-00003-C02-01). C. Arribas was supported by a PhD contract from INIA. The authors are also grateful to FCT, Portugal and FEDER under Programme PT2020 for financial support to CIMO (UID/AGR/00690/2013).pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationArribas, Claudia; Pereira, Eliana; Barros, Lillian; Guillamón, E.; Ferreira, Isabel C.F.R.; Pedrosa, M.M. (2017). Tocopherols content in gluten-free extruded composite flours of rice and different legumes. In 10º Encontro Nacional de Cromatografia. Bragança. ISBN 978-972-745-234-7pt_PT
dc.identifier.isbn978-972-745-234-7
dc.identifier.urihttp://hdl.handle.net/10198/15704
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherInstituto Politécnico de Bragançapt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.titleTocopherols content in gluten-free extruded composite flours of rice and different legumespt_PT
dc.typeconference object
dspace.entity.typePublication
oaire.citation.conferencePlaceBragança, Portugalpt_PT
oaire.citation.title10º Encontro Nacional de Cromatografiapt_PT
person.familyNamePereira
person.familyNameBarros
person.familyNameFerreira
person.givenNameEliana
person.givenNameLillian
person.givenNameIsabel C.F.R.
person.identifier469085
person.identifier144781
person.identifier.ciencia-idBE17-462D-9A75
person.identifier.ciencia-id9616-35CB-D001
person.identifier.ciencia-id9418-CF95-9919
person.identifier.orcid0000-0003-2854-6745
person.identifier.orcid0000-0002-9050-5189
person.identifier.orcid0000-0003-4910-4882
person.identifier.ridQ-8017-2018
person.identifier.ridJ-3600-2013
person.identifier.ridE-8500-2013
person.identifier.scopus-author-id55938912300
person.identifier.scopus-author-id35236343600
person.identifier.scopus-author-id36868826600
rcaap.rightsopenAccesspt_PT
rcaap.typeconferenceObjectpt_PT
relation.isAuthorOfPublicationdda60cdc-0a2a-4c10-863e-eaef1e6f1fb9
relation.isAuthorOfPublication3af07ffe-f914-48ba-a5d5-efcf70fdce01
relation.isAuthorOfPublicationbd0d1537-2e03-41fb-b27a-140af9c35db8
relation.isAuthorOfPublication.latestForDiscoverydda60cdc-0a2a-4c10-863e-eaef1e6f1fb9

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