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Key parameters when developing carbonaceous materials for catalytic wet peroxide oxidation

dc.contributor.authorRibeiro, Rui
dc.contributor.authorSilva, Adrián
dc.contributor.authorPastrana-Martínez, Luisa
dc.contributor.authorFigueiredo, José
dc.contributor.authorFaria, Joaquim
dc.contributor.authorGomes, Helder
dc.date.accessioned2014-12-04T12:52:32Z
dc.date.available2014-12-04T12:52:32Z
dc.date.issued2014
dc.description.abstractCatalytic wet peroxide oxidation (CWPO) is an advanced oxidation process, operated using simple equipment and mild operating conditians, in which highly oxidizing hydraxyl radicaIs (HO') are generated fram the catalytic decompasition af hydrogen peroxide (H,O,) [L 2). Sinee the report of Lüeking el ai. in 1998 [3], the develapment af suitab-Ie -carbonaceous materials (without any added metal phase) for CWPO has been intensively explored [4). lhe influenee of struetUfal and surraee chemical features on their adsorption and catalytic performance was also a subject of study and discussion. In lhe present work, gathering the Imowledge acquired in the last few years in several publications of our research graup, some crucial praperties that should be combined when developing carbonaceous materiais for CWPO applications are identified (cf Figure la) and thoroughly explored. For instanee, graphene-based materiaIs were recently reported as active and stable catalysts for the CWPO of high1y eoneentrated 4-nitrophenol solutions (5 g L" ), the main aetive sites being at electran rich regions generated Eram the confinement af delocalized rr-electrans caused by structural defects [5]. The mechanism over these active sites involves the reductive decomposition oEH201 to generate HO', as shown in Figure lb.por
dc.identifier.citationRibeiro, Rui S.; Silva, Adrián M.T.; Pastrana-Martínez, Luisa M.; Figueiredo, José L.; Faria, Joaquim L.; Gomes, Helder (2014). Key parameters when developing carbonaceous materials for catalytic wet peroxide oxidation. In XX Encontro Luso-Galego de Química. Porto.por
dc.identifier.urihttp://hdl.handle.net/10198/11417
dc.language.isoengpor
dc.peerreviewedyespor
dc.titleKey parameters when developing carbonaceous materials for catalytic wet peroxide oxidationpor
dc.typeconference object
dspace.entity.typePublication
oaire.citation.conferencePlacePortopor
oaire.citation.startPage45por
oaire.citation.titleXX Encontro Luso-Galego de Químicapor
person.familyNameGomes
person.givenNameHelder
person.identifier.ciencia-id6218-1E19-13EE
person.identifier.orcid0000-0001-6898-2408
rcaap.rightsopenAccesspor
rcaap.typeconferenceObjectpor
relation.isAuthorOfPublication0eb96337-224a-4339-9918-334436fbbb99
relation.isAuthorOfPublication.latestForDiscovery0eb96337-224a-4339-9918-334436fbbb99

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