Publication
Synthesis of new hydroxy-2-styrylchromones
dc.contributor.author | Santos, Clementina M.M. | |
dc.contributor.author | Silva, Artur | |
dc.contributor.author | Cavaleiro, José | |
dc.date.accessioned | 2011-04-04T14:41:34Z | |
dc.date.available | 2011-04-04T14:41:34Z | |
dc.date.issued | 2003 | |
dc.description | http://apps.isiknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=5&SID=V1M67gPH3IpI7j5a98j&page=1&doc=1&colname=WOS | |
dc.description.abstract | Hydroxy-2-styrylchromones 5a−i were prepared by debenzylation of benzyloxy-2-styrylchromones 3a−i, which were synthesised by the Baker−Venkataraman method. The last step of this method, the cyclodehydration 5-aryl-3-hydroxy- 1-(2-hydroxyaryl)-2,4-pentadien-1-ones 2a−i, was carried out with a catalytic amount of iodine, or p-toluenesulfonic acid, in DMSO. Benzyloxy-3-cinnamoyl-2-styrylchromones 4a−f were obtained as by-products in both procedures, but the latter procedure gave benzyloxy-2- styrylchromones 3a−i in better yields. The structures of all new compounds were established by extensive NMR studies. | por |
dc.identifier.citation | Santos, Clementina; Silva, Artur; Cavaleiro, José (2003). Synthesis of new hydroxy-2-styrylchromones. European Journal of Organic Chemistry. ISSN 1434-193X. 23, p. 4575-4585 | por |
dc.identifier.doi | 10.1002/ejoc.200300468 | |
dc.identifier.issn | 1434-193X | |
dc.identifier.uri | http://hdl.handle.net/10198/3932 | |
dc.language.iso | eng | por |
dc.peerreviewed | yes | por |
dc.publisher | Wiley | por |
dc.subject | Rearrangements | por |
dc.subject | Cyclizations | por |
dc.subject | Protecting groups | por |
dc.subject | Heterocycles | por |
dc.title | Synthesis of new hydroxy-2-styrylchromones | por |
dc.type | journal article | |
dspace.entity.type | Publication | |
oaire.citation.endPage | 4585 | por |
oaire.citation.startPage | 4575 | por |
oaire.citation.title | European Journal of Organic Chemistry | por |
person.familyName | Santos | |
person.givenName | Clementina M.M. | |
person.identifier.ciencia-id | 9018-DB9C-C590 | |
person.identifier.orcid | 0000-0003-4380-7990 | |
person.identifier.scopus-author-id | 7201458663 | |
rcaap.rights | openAccess | por |
rcaap.type | article | por |
relation.isAuthorOfPublication | 64f662b6-775d-4ea0-bfd7-f527af0ac1a0 | |
relation.isAuthorOfPublication.latestForDiscovery | 64f662b6-775d-4ea0-bfd7-f527af0ac1a0 |