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Synthesis of new hydroxy-2-styrylchromones

dc.contributor.authorSantos, Clementina M.M.
dc.contributor.authorSilva, Artur
dc.contributor.authorCavaleiro, José
dc.date.accessioned2011-04-04T14:41:34Z
dc.date.available2011-04-04T14:41:34Z
dc.date.issued2003
dc.descriptionhttp://apps.isiknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=5&SID=V1M67gPH3IpI7j5a98j&page=1&doc=1&colname=WOS
dc.description.abstractHydroxy-2-styrylchromones 5a−i were prepared by debenzylation of benzyloxy-2-styrylchromones 3a−i, which were synthesised by the Baker−Venkataraman method. The last step of this method, the cyclodehydration 5-aryl-3-hydroxy- 1-(2-hydroxyaryl)-2,4-pentadien-1-ones 2a−i, was carried out with a catalytic amount of iodine, or p-toluenesulfonic acid, in DMSO. Benzyloxy-3-cinnamoyl-2-styrylchromones 4a−f were obtained as by-products in both procedures, but the latter procedure gave benzyloxy-2- styrylchromones 3a−i in better yields. The structures of all new compounds were established by extensive NMR studies.por
dc.identifier.citationSantos, Clementina; Silva, Artur; Cavaleiro, José (2003). Synthesis of new hydroxy-2-styrylchromones. European Journal of Organic Chemistry. ISSN 1434-193X. 23, p. 4575-4585por
dc.identifier.doi10.1002/ejoc.200300468
dc.identifier.issn1434-193X
dc.identifier.urihttp://hdl.handle.net/10198/3932
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherWileypor
dc.subjectRearrangementspor
dc.subjectCyclizationspor
dc.subjectProtecting groupspor
dc.subjectHeterocyclespor
dc.titleSynthesis of new hydroxy-2-styrylchromonespor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage4585por
oaire.citation.startPage4575por
oaire.citation.titleEuropean Journal of Organic Chemistrypor
person.familyNameSantos
person.givenNameClementina M.M.
person.identifier.ciencia-id9018-DB9C-C590
person.identifier.orcid0000-0003-4380-7990
person.identifier.scopus-author-id7201458663
rcaap.rightsopenAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication64f662b6-775d-4ea0-bfd7-f527af0ac1a0
relation.isAuthorOfPublication.latestForDiscovery64f662b6-775d-4ea0-bfd7-f527af0ac1a0

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