Repository logo
 
Publication

Hybrid multi-core shell magnetic nanoparticles for wet peroxide oxidation of paracetamol: application in synthetic and real matrices

2023Journal article Open access
Simple item page
dc.contributor.authorSilva, Adriano S.
dc.contributor.authorRoman, Fernanda
dc.contributor.authorDias, Arnaldo
dc.contributor.authorDíaz de Tuesta, Jose Luis
dc.contributor.authorNarcizo, Alexandre
dc.contributor.authorSilva, Ana P. F.
dc.contributor.authorÇaha, Ihsan
dc.contributor.authorDeepak, Francis Leonard
dc.contributor.authorBañobre-López, Manuel
dc.contributor.authorFerrari, Ana M.
dc.contributor.authorGomes, Helder
dc.date.accessioned2023-12-19T09:57:59Z
dc.date.available2023-12-19T09:57:59Z
dc.date.issued2023
dc.description.abstractClean water availability is becoming a matter of global concern in the last decades. The responsible entities for wastewater treatment do not have the proper facilities to deal with a wide range of pollutants. Special attention should be given to emerging contaminants, whose presence in water bodies may cause adverse effects on the aquatic ecosystem and human health. Most studies in the literature do not consider the development of their solution in real matrices, which can hinder the applicability of the explored alternative in the real scenario. Therefore, in this work, we demonstrate the applicability of hybrid magnetic nanoparticles for removing paracetamol (PCM) from simulated and real matrices by catalytic wet peroxide oxidation (CWPO). To achieve carbon coating, the nanoparticles were prepared via the traditional route (resorcinol/formaldehyde, CoFe@CRF). A new methodology was also considered for synthesizing thin-layered carbon-coated magnetic nanoparticles (phloroglucinol/ glyoxalic acid, CoFe@CPG). TEM images revealed a multi-core shell structure formation, with an average carbon layer size of 7.8 ± 0.5 and 3.2 ± 0.3 nm for resorcinol/formaldehyde and phloroglucinol/ glyoxalic acid methodology, respectively. Screening the materials’ activity for PCM oxidation by CWPO revealed that the nanoparticle prepared by phloroglucinol/glyoxalic acid methodology has higher performance for the degradation of PCM, achieving 63.5% mineralization after 24 h of reaction, with similar results for more complex matrices. Iron leaching measured at the end of all reactions has proven that the carbon layer protects the core against leaching.pt_PT
dc.description.sponsorshipThis work was financially supported by project RTChip4Theranostics (NORTE-01–0145-FEDER-029394), by CIMO (UIDB/00690/2020) through FEDER under Program PT2020. Fernanda F. Roman acknowledges the Foundation for Science and Technology (FCT) and the European Social Fund (FSE) for the individual research grant with reference SFRH/BD/143224/2019. Adriano Silva and Ana Paula F. da Silva were supported by the doctoral Grant SFRH/BD/151346/2021 and PRT/BD/ 153090/2021 financed by the Portuguese Foundation for Science and Technology (FCT) with funds from NORTE2020, under MIT Portugal Program. Jose L. Diaz De Tuesta acknowledges the financial support through the program of Atracción al Talento of Comunidad de Madrid (Spain) for the individual research grant 2022-T1/AMB-23946.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationSilva, Adriano S.; Roman, Fernanda; Dias, Arnaldo; Díaz de Tuesta, Jose Luis; Narcizo, Alexandre; Silva, Ana Paula; Çaha, Ihsan; Deepak, Francis Leonard; Bañobre-López, Manuel; Ferrari, Ana M.; Gomes, Helder (2023). Hybrid multi-core shell magnetic nanoparticles for wet peroxide oxidation of paracetamol: application in synthetic and real matrices. Journal of Environmental Chemical Engineering. ISSN 2213-2929. 11:5, p. 1-10pt_PT
dc.identifier.doi10.1016/j.jece.2023.110806pt_PT
dc.identifier.eissn2213-3437
dc.identifier.issn2213-2929
dc.identifier.urihttp://hdl.handle.net/10198/28969
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationMountain Research Center
dc.relationAmphiphilic carbon-based materials for one-pot desulfurization and denitrogenation of liquid fuels
dc.relationMonitoring of municipal waste streams and their transformation into geopolymers
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectHeterogeneous fentonpt_PT
dc.subjectContaminants of emerging concernpt_PT
dc.subjectReal wastewaterpt_PT
dc.subjectAdvanced oxidation processpt_PT
dc.subjectMicropollutantspt_PT
dc.subjectCarbon-coated nanoparticlept_PT
dc.titleHybrid multi-core shell magnetic nanoparticles for wet peroxide oxidation of paracetamol: application in synthetic and real matricespt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleMountain Research Center
oaire.awardTitleAmphiphilic carbon-based materials for one-pot desulfurization and denitrogenation of liquid fuels
oaire.awardTitleMonitoring of municipal waste streams and their transformation into geopolymers
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00690%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/POR_NORTE/SFRH%2FBD%2F143224%2F2019/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/POR_NORTE/SFRH%2FBD%2F151346%2F2021/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/OE/PRT%2FBD%2F153090%2F2021/PT
oaire.citation.endPage10pt_PT
oaire.citation.issue5pt_PT
oaire.citation.startPage1pt_PT
oaire.citation.titleJournal of Environmental Chemical Engineeringpt_PT
oaire.citation.volume11pt_PT
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStreamPOR_NORTE
oaire.fundingStreamPOR_NORTE
oaire.fundingStreamOE
person.familyNameSilva
person.familyNameRoman
person.familyNameDíaz de Tuesta
person.familyNameSilva
person.familyNameGomes
person.givenNameAdriano S.
person.givenNameFernanda
person.givenNameJose Luis
person.givenNameAna P. F.
person.givenNameHelder
person.identifierhttps://www.researchgate.net/profile/Ana-Ferreira-Da-Silva-3
person.identifier.ciencia-id3E14-5049-B09D
person.identifier.ciencia-idEE1B-DAA7-D0BD
person.identifier.ciencia-id7A1F-022B-7DBF
person.identifier.ciencia-id991F-2DB8-3246
person.identifier.ciencia-id6218-1E19-13EE
person.identifier.orcid0000-0002-6795-2335
person.identifier.orcid0000-0001-5360-5298
person.identifier.orcid0000-0003-2408-087X
person.identifier.orcid0000-0001-8979-8407
person.identifier.orcid0000-0001-6898-2408
person.identifier.ridD-9785-2017
person.identifier.scopus-author-id55755821600
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication3ba90ba4-aac8-4892-a30f-25a10bc27298
relation.isAuthorOfPublicationc145030b-c811-4be4-b6af-1926e364cb33
relation.isAuthorOfPublication2ad0465f-5f8a-4b14-90f5-bf85996f9ce1
relation.isAuthorOfPublication729b6629-41f1-4699-9630-9a32f38df4e5
relation.isAuthorOfPublication0eb96337-224a-4339-9918-334436fbbb99
relation.isAuthorOfPublication.latestForDiscovery3ba90ba4-aac8-4892-a30f-25a10bc27298
relation.isProjectOfPublication29718e93-4989-42bb-bcbc-4daff3870b25
relation.isProjectOfPublication35216b99-752d-46d1-bc41-63ab229a78fe
relation.isProjectOfPublicationd0ef49be-0e60-4aa7-bc5f-a34f26edb73e
relation.isProjectOfPublication91a402c0-2c8d-4e39-b8f0-245054eb302f
relation.isProjectOfPublication.latestForDiscoveryd0ef49be-0e60-4aa7-bc5f-a34f26edb73e

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
1-s2.0-S2213343723015452-main.pdf
Size:
2.83 MB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.75 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

CIMO - Artigos em Revistas Indexados à WoS/Scopus