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Acid leaching of alloys within the quaternary system Fe-Si-Ca-Al

dc.contributor.authorMargarido, Fernanda
dc.contributor.authorFigueiredo, Maria Ondina
dc.contributor.authorQueiroz, Ana
dc.contributor.authorMartins, João Pedro de Almeida
dc.date.accessioned2010-02-11T18:28:52Z
dc.date.available2010-02-11T18:28:52Z
dc.date.issued1997
dc.description.abstractSilicon with high purity and fine particle size can be produced by acid leaching of Fe-Si industrial alloys under the condition that they have adequate chemical composition and structural constitution. Such alloys contain phases that fall within the system Fe-Si-Ca-Al, where the quaternary phase Caalsifer, with aproximate formula (Fe0.8Al0.1 0.1) (Si0.8Ca0.2)2, is found along with several binary and ternary phases (Fe-Si, Ca-Si, Al-Fe-Si, Ca-Al-Si). With the purpose of optimizing the phase, constitution alloys were synthesized within the system Fe-Si-Ca-Al. The results of leaching experiments performed using HCl (150 and 220g/L) at constant temperature (T=102 1 C) and ordinary atmosphere indicate that the Caalsifer plus Al-Fe-Si phases should be maximized whereas the FeSi2 phases should be minimized, by controlling Al/Ca and Fe/Si concentration ratios in the synthesis process.pt
dc.identifier.citationMargarido, F.; Figueiredo, M.O.; Queiroz, A.M.; Martins, J.I. (1997). Acid leaching of alloys within the quaternary system Fe-Si-Ca-Al. Industrial & Engineering Chemistry Research. ISSN 1520-5045. 36:12 p.5291–5295pt
dc.identifier.doi10.1021/ie970295y
dc.identifier.issn1520-5045
dc.identifier.urihttp://hdl.handle.net/10198/1858
dc.language.isoengpt
dc.publisherACSpt
dc.subjectAcid leaching refiningpt
dc.subjectSynthesised alloyspt
dc.titleAcid leaching of alloys within the quaternary system Fe-Si-Ca-Alpt
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage5295pt
oaire.citation.issue36(12)pt
oaire.citation.startPage5291pt
oaire.citation.titleIndustrial and Engineering Chemistry Researchpt
person.familyNameQueiroz
person.givenNameAna
person.identifier.ciencia-id2611-D40C-3472
person.identifier.orcid0000-0003-4761-0618
person.identifier.ridO-8367-2015
rcaap.rightsopenAccesspt
rcaap.typearticlept
relation.isAuthorOfPublication508436a2-5db1-481e-9c48-eab160333d61
relation.isAuthorOfPublication.latestForDiscovery508436a2-5db1-481e-9c48-eab160333d61

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