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Carbon nanotubes as base materials for water treatment processes

dc.contributor.authorFaria, Joaquim
dc.contributor.authorRibeiro, Rui
dc.contributor.authorSilva, Adrián
dc.contributor.authorSilva, Cláudia
dc.contributor.authorFigueiredo, José
dc.contributor.authorGomes, Helder
dc.date.accessioned2013-11-19T13:30:54Z
dc.date.available2013-11-19T13:30:54Z
dc.date.issued2013
dc.description.abstractChemical wastewater treatments are dependent on the addition of auxiliary oxidants, which may include molecular oxygen, ozone, and hydrogen peroxide, working on their own, or activated by means of a specialized catalyst or photocatalyst. Chemical treatments are by nature definitive processes, since they can lead to complete mineralization of the existing pollutants. However, this is seldom the case, when looking for a rational solution from the socio-economical point of view. In the case of industrial effluents, special treatments are often required, even when only a partial oxidative degradation is targeted, due to the complex nature of the pollutants (e.g. dyes, pharmaceuticals, oils, organics, inorganics and bio-compounds). Some compounds, like nitrophenols, are particularly refractory to aerobic biodegradation and in addition to that toxic, requiring strong oxidative solutions. Typical solutions are the thermal processes at elevated temperatures and pressures, or using metal supported catalysts. Alternatively, it is possible to use heterogeneous photocatalysis based on the efficient production of hydroxyl radicals. Somewhere between these two limits lies the catalytic wet peroxide oxidation (CWPO), an advanced oxidation process (AOP) involving the use of hydrogen peroxide (H2O2) as oxidation source and a suitable catalyst (typically iron based catalysts). The main role of the catalyst is to promote H2O2 decomposition through the formation of hydroxyl radicals (HO●) with high oxidizing potential, effective in the destruction of a huge range of pollutants [1,2]. This type of technology is especially attractive due to the use of mild conditions, simple equipment and the environmental safe oxidant H2O2.
dc.description.sponsorshipWork supported by project PTDC/AAC-AMB/110088/2009 and partially by project PEst–C/EQB/LA0020/2011, financed by FEDER through COMPETE - Programa Operacional Factores de Competitividade and by FCT - Fundação para a Ciência e a Tecnologia.
dc.identifier.citationFaria, Joaquim L.,; Ribeiro Rui S.; Silva Adrián M.T.; Silva C.G., Figueiredo José L.; Gomes Helder (2013). Carbon nanotubes as base materials for water treatment processes, In CESEP’ 13 - 5th International Conference on Carbon for Energy Storage/Conversion and Environment Protection. Mülheim a.d. Ruhr, Alemanha.por
dc.identifier.urihttp://hdl.handle.net/10198/8981
dc.language.isoengpor
dc.peerreviewedyespor
dc.relationPEst–C/EQB/LA0020/2011
dc.relationDegradation of organic pollutants by catalytic wet peroxide oxidation using carbon materials
dc.titleCarbon nanotubes as base materials for water treatment processespor
dc.typeconference object
dspace.entity.typePublication
oaire.awardTitleDegradation of organic pollutants by catalytic wet peroxide oxidation using carbon materials
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876-PPCDTI/PTDC%2FAAC-AMB%2F110088%2F2009/PT
oaire.citation.conferencePlaceMülheim a.d. Ruhr, Alemanhapor
oaire.citation.titleCESEP’ 13 - 5th International Conference on Carbon for Energy Storage/Conversion and Environment Protectionpor
oaire.fundingStream5876-PPCDTI
person.familyNameGomes
person.givenNameHelder
person.identifier.ciencia-id6218-1E19-13EE
person.identifier.orcid0000-0001-6898-2408
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspor
rcaap.typeconferenceObjectpor
relation.isAuthorOfPublication0eb96337-224a-4339-9918-334436fbbb99
relation.isAuthorOfPublication.latestForDiscovery0eb96337-224a-4339-9918-334436fbbb99
relation.isProjectOfPublication423797ec-e3f2-4dfd-9912-a7dbff024234
relation.isProjectOfPublication.latestForDiscovery423797ec-e3f2-4dfd-9912-a7dbff024234

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