Publication
Dynamic study of the synthesis of 1,1-dibutoxyethane in a fixed-bed adsorptive reactor
| dc.contributor.author | Graça, Nuno S. | |
| dc.contributor.author | Pais, Luís S. | |
| dc.contributor.author | Silva, Viviana M.T.M. | |
| dc.contributor.author | Rodrigues, Alírio | |
| dc.date.accessioned | 2011-06-09T11:24:35Z | |
| dc.date.available | 2011-06-09T11:24:35Z | |
| dc.date.issued | 2011 | |
| dc.description.abstract | The synthesis of 1,1-Dibutoxyethane in a fixed-bed adsorptive reactor using Amberlyst 15 was studied for the first time. The adsorption of non-reactive pairs was investigated experimentally, at 25 °C, by frontal chromatography in a fixed-bed adsorber. In order to avoid the immiscibility of the liquid phase, the liquid-liquid equilibrium for the mixture 1-butanol/water was studied. The multicomponent equilibrium adsorption data was assumed to follow the modified Langmuir type isotherm. Reaction experiments of 1,1-Dibutoxyethane production and column regeneration were performed in the fixed-bed adsorptive reactor. This work will enable further developments in chromatographic reactors aiming at the 1,1-Dibutoxyethane process intensification. | por |
| dc.identifier.citation | Graça, N.S.; Pais, L.S.; Silva, V.M.T.M.; Rodrigues, A.E. (2011). Dynamic study of the synthesis of 1,1-dibutoxyethane in a fixed-bed adsorptive reactor. Separation Science Technolology. ISSN 0149-6395. 46, p. 631-640 | por |
| dc.identifier.doi | 10.1080/01496395.2010.534121 | |
| dc.identifier.eissn | 1520-5754 | |
| dc.identifier.issn | 0149-6395 | |
| dc.identifier.uri | http://hdl.handle.net/10198/5092 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | Taylor & Francis | |
| dc.subject | 1,1-Dibutoxyethane | por |
| dc.subject | Fixed-bed adsorptive reactor | por |
| dc.subject | Process intensification | por |
| dc.title | Dynamic study of the synthesis of 1,1-dibutoxyethane in a fixed-bed adsorptive reactor | por |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 640 | por |
| oaire.citation.startPage | 631 | por |
| oaire.citation.title | Separation Science Technolology | por |
| person.familyName | Pais | |
| person.givenName | Luís S. | |
| person.identifier.ciencia-id | 421E-0CCD-A84F | |
| person.identifier.orcid | 0000-0002-3000-2862 | |
| person.identifier.scopus-author-id | 6603930478 | |
| rcaap.rights | openAccess | por |
| rcaap.type | article | por |
| relation.isAuthorOfPublication | c6d25534-8487-45b1-90af-d350f4e3ac55 | |
| relation.isAuthorOfPublication.latestForDiscovery | c6d25534-8487-45b1-90af-d350f4e3ac55 |