Publicação
Unveiling the mechanism of hydrotropy: Evidence for water-mediated aggregation of hydrotropes around the solute
| dc.contributor.author | Abranches, Dinis O. | |
| dc.contributor.author | Benfica, Jordana | |
| dc.contributor.author | Soares, Bruna de Paula | |
| dc.contributor.author | Leal-Duaso, Alejandro | |
| dc.contributor.author | Sintra, Tânia E. | |
| dc.contributor.author | Pires, Elísabet | |
| dc.contributor.author | Pinho, Simão | |
| dc.contributor.author | Shimizu, Seishi | |
| dc.contributor.author | Coutinho, João A.P. | |
| dc.date.accessioned | 2018-02-19T10:00:00Z | |
| dc.date.accessioned | 2021-02-27T16:30:57Z | |
| dc.date.available | 2018-01-19T10:00:00Z | |
| dc.date.available | 2021-02-27T16:30:57Z | |
| dc.date.issued | 2020 | |
| dc.description.abstract | A recent proposal attributes the origin of hydrotropy to the water-mediated aggregation of hydrotrope molecules around the solute. Experimental evidence for this phenomenon is reported for the first time in this work, using 1H-NMR. A new computational technique to quantify apolarity is introduced and is used to show that apolarity of both solute and hydrotrope is the driving force of hydrotropy. This journal is | en_EN |
| dc.description.sponsorship | This work was developed within the scope of the projects CICECO-Aveiro Institute of Materials, UIDB/50011/2020 & UIDP/50011/2020, and CIMO-Mountain Research Center, UIDB/00690/2020, both financed by national funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement. The NMR spectrometers are part of the National NMR Network (PTNMR) and are partially supported by Infrastructure Project No. 022161 (co-financed by FEDER through COMPETE 2020, POCI and PORL and FCT through PIDDAC). Financial support from Ministerio de Ciencia, Innovacio ´n (project RTI2018-093431-B-I00) and the Gobierno de Arago´n (Group E37_17R) co-funded by FEDER 2014-2020 ‘‘Construyendo Europa desde Aragón’’ is acknowledged. B. P. S. acknowledges FCT for her PhD grant SFRH/BD/138439/2018. | |
| dc.description.version | info:eu-repo/semantics/publishedVersion | en_EN |
| dc.identifier.citation | Abranches, Dinis O.; Benfica, Jordana; Soares, Bruna P.; Leal-Duaso, Alejandro; Sintra, Tânia E.; Pires, Elísabet; Pinho, Simão P.; Shimizu, Seishi; Coutinho, João A.P. (2020). Unveiling the mechanism of hydrotropy: Evidence for water-mediated aggregation of hydrotropes around the solute. Chemical Communications. ISSN 1359-7345. 56:52, p. 7143-7146 | en_EN |
| dc.identifier.doi | 10.1039/d0cc03217d | en_EN |
| dc.identifier.issn | 1359-7345 | |
| dc.identifier.uri | http://hdl.handle.net/10198/23401 | |
| dc.language.iso | eng | |
| dc.peerreviewed | yes | en_EN |
| dc.relation | RTI2018-093431-B-I00 | |
| dc.title | Unveiling the mechanism of hydrotropy: Evidence for water-mediated aggregation of hydrotropes around the solute | en_EN |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| person.familyName | Pinho | |
| person.givenName | Simão | |
| person.identifier | 810882 | |
| person.identifier.ciencia-id | 481D-73AD-8D0F | |
| person.identifier.orcid | 0000-0002-9211-857X | |
| person.identifier.rid | D-4148-2013 | |
| person.identifier.scopus-author-id | 7003570175 | |
| rcaap.rights | openAccess | en_EN |
| rcaap.type | article | en_EN |
| relation.isAuthorOfPublication | 8ef7789a-34f3-4915-a666-4efe26272a30 | |
| relation.isAuthorOfPublication.latestForDiscovery | 8ef7789a-34f3-4915-a666-4efe26272a30 |