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A complete separation of hexane isomers by a functionalized flexible metal organic framework

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dc.contributor.authorMendes, Patrícia A.P.
dc.contributor.authorHorcajada, Patricia
dc.contributor.authorRives, Sébastien
dc.contributor.authorRen, Hong
dc.contributor.authorRodrigues, Alírio
dc.contributor.authorDevic, Thomas
dc.contributor.authorMagnier, Emmanuel
dc.contributor.authorTrens, Philippe
dc.contributor.authorJobic, Hervé
dc.contributor.authorOllivier, Jacques
dc.contributor.authorMaurin, Guillaume
dc.contributor.authorSerre, Christian
dc.contributor.authorSilva, José A.C.
dc.date.accessioned2015-12-21T16:41:20Z
dc.date.available2015-12-21T16:41:20Z
dc.date.issued2014
dc.description.abstractThe separation ability of branched alkane isomers (nHEX, 3MP, 22DMB) of the flexible and functionalized microporous iron(III) dicarboxylate MIL-53(Fe)-(CF3)2 solid is evaluated through a combination of breakthrough experiments (binary or ternary mixtures), adsorption isotherms, X-ray diffraction temperature analysis, quasi-elastic neutron scattering measurements and molecular dynamics simulations. A kinetically controlled molecular sieve separation between the di-branched isomer of hexane 22DMB from a mixture of paraffins is achieved. The reported total separation between mono- and di-branched alkanes which was neither predicted nor observed so far in any class of porous solids is spectacular and paves the way towards a potential unprecedented upgrading of the RON of gasoline.pt_PT
dc.identifier.citationMendes, Patricia A. P.; Horcajada, Patricia; Rives, Sébastien; Ren, Hong; Rodrigues, A.E.; Devic, Thomas; Magnier, Emmanuel; Trens, Philippe; Jobic, Hervé; Ollivier, Jacques; Maurin, Guillaume; Serre, Christian; Silva, José A.C. (2014). A complete separation of hexane isomers by a functionalized flexible metal organic framework. Advanced Functional Materials. ISSN 1616-3028. 8:24, p.7666-7673pt_PT
dc.identifier.doi10.1002/adfm.201401974pt_PT
dc.identifier.issn1616-3028
dc.identifier.urihttp://hdl.handle.net/10198/12534
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherWiley-VCHpt_PT
dc.relation(FP7/2007-2013) nº 228862
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectHexane isomerspt_PT
dc.subjectFunctionalised MOFspt_PT
dc.titleA complete separation of hexane isomers by a functionalized flexible metal organic frameworkpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage7673pt_PT
oaire.citation.issue24pt_PT
oaire.citation.startPage7666pt_PT
oaire.citation.titleAdvanced Functional Materialspt_PT
oaire.citation.volume8pt_PT
person.familyNameSilva
person.givenNameJosé A.C.
person.identifier.ciencia-idC11B-F5CF-7C78
person.identifier.orcid0000-0003-1778-3833
person.identifier.scopus-author-id7403023684
rcaap.rightsrestrictedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication16366ede-a7d6-45ff-a8c9-eff9bdde35c7
relation.isAuthorOfPublication.latestForDiscovery16366ede-a7d6-45ff-a8c9-eff9bdde35c7

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