Publication
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
| dc.contributor.author | Bastin, Laurent | |
| dc.contributor.author | Bárcia, Patrick da Silva | |
| dc.contributor.author | Hurtado, Eric | |
| dc.contributor.author | Silva, José A.C. | |
| dc.contributor.author | Rodrigues, Alírio | |
| dc.contributor.author | Chen, Banglin | |
| dc.date.accessioned | 2011-02-04T16:04:09Z | |
| dc.date.available | 2011-02-04T16:04:09Z | |
| dc.date.issued | 2008 | |
| dc.description.abstract | A microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N-2 and CO2/CH4 and ternary CO2/CH4/N-2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 x 4.0 angstrom to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO2 with the,adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential. applications in this very important industrial and environmental process. | por |
| dc.identifier.citation | Bastin, Laurent; Barcia, Patrick; Hurtado, Eric; Silva, Jose A. C.; Rodrigues, Alirio; Chen, Banglin (2008). A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption. Journal od Physical Chemistry C. ISSN 1932-7447. 112:5, p. 1575-1581 | por |
| dc.identifier.doi | 10.1021/jp077618g | |
| dc.identifier.issn | 1932-7447 | |
| dc.identifier.uri | http://hdl.handle.net/10198/3271 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | American Chemical Society | por |
| dc.subject | Adsorption | por |
| dc.title | A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption | por |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.title | The Journal of physical chemistry | por |
| person.familyName | Silva | |
| person.givenName | José A.C. | |
| person.identifier.ciencia-id | C11B-F5CF-7C78 | |
| person.identifier.orcid | 0000-0003-1778-3833 | |
| person.identifier.scopus-author-id | 7403023684 | |
| rcaap.rights | openAccess | por |
| rcaap.type | article | por |
| relation.isAuthorOfPublication | 16366ede-a7d6-45ff-a8c9-eff9bdde35c7 | |
| relation.isAuthorOfPublication.latestForDiscovery | 16366ede-a7d6-45ff-a8c9-eff9bdde35c7 |
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