Repository logo
 
Publication

Development of colloidal lignin particles through particle design strategies and screening of their Pickering stabilizing potential

2023Journal article Open access
Simple item page
dc.contributor.authorColucci, Giovana
dc.contributor.authorSantamaria-Echart, Arantzazu
dc.contributor.authorSilva, Samara Cristina
dc.contributor.authorTeixeira, Liandra Gracher
dc.contributor.authorRibeiro, Andreia
dc.contributor.authorRodrigues, Alírio
dc.contributor.authorBarreiro, M.F.
dc.date.accessioned2020-03-04T09:34:17Z
dc.date.available2020-03-04T09:34:17Z
dc.date.issued2023
dc.description.abstractColloidal lignin particles (CLPs) have increased interest as green and sustainable materials for Pickering stabilizers, with particle design being an important step towards their effective use. In this context, the antisolvent precipitation method was selected to conduct a study aiming at understanding the effect of process variables (initial lignin concentration, antisolvent pH, final ethanol concentration, and antisolvent addition rate) on particle size, zeta potential, color parameters, and contact angle. Moreover, their Pickering stabilizing potential was preliminarily screened. The evaluation using a Fractional Factorial Design revealed that the particle size is significantly influenced by the initial lignin concentration (as it increases, larger particles are obtained) and the final ethanol concentration (as it increases, smaller sizes result). The zeta potential is significantly affected by the antisolvent pH and the initial lignin concentration; the increase in both parameters results in higher negative values. The color is significantly dependent on the used initial lignin concentration (as it increases, particles become lighter and the yellowish accentuates) and the antisolvent pH (as it increases, particles become darker). Both initial lignin concentration and final ethanol concentration increase promote hydrophobicity, whereas increasing the antisolvent pH and its addition rate turns particles more hydrophilic. Through this strategy, it was possible to achieve CLPs with promising Pickering stabilizing potential, putting in evidence the importance of understanding the production process to design effective particles for target applications.pt_PT
dc.description.sponsorshipThe authors are grateful to the Foundation for Science and Technology (FCT, Portugal) for financial support through national funds FCT/MCTES (PIDDAC) to CIMO (UIDB/00690/2020 and UIDP/00690/ 2020), SusTEC (LA/P/0007/2021), LSRE-LCM (UIDB/50020/2020 and UIDP/00690/2020), and ALiCE (LA/P/0045/2020). National funding by FCT, P.I., through the institutional scientific employment program contract of A. Santamaria-Echart. FCT for the Ph.D. research grants of G. Colucci (2021.05215. BD), S.C. Silva (SFRH/BD/148281/2019), and L. G. Teixeira (2020.08803. BD). ValorNatural for A. Ribeiro contract (Norte01–0247-FEDER-024479). i3S Scientific Platform HEMS, member of the national infrastructure PPBI - Portuguese Platform of Bioimaging (PPBI-POCI-01–0145-FEDER-022122). Ingevity™ for the kind supply of Indulin AT lignin. COST Action LignoCOST (CA17128), supported by COST (European Cooperation in Science and Technology), in promoting interaction, exchange of knowledge, and collaborations in the field of lignin valorization.
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationColucci, Giovana; Santamaria-Echart, Arantzazu; Silva, Samara Cristina; Teixeira, Liandra Gracher; Ribeiro, Andreia; Rodrigues, Alírio; Barreiro, M.F. (2023). Development of colloidal lignin particles through particle design strategies and screening of their Pickering stabilizing potential. Colloids and Surfaces A-Physicochemical and Engineering Aspects. eISSN 1873-4359. 666, p. 1-10pt_PT
dc.identifier.doi10.1016/j.colsurfa.2023.131287
dc.identifier.eissn1873-4359
dc.identifier.issn0927-7757
dc.identifier.urihttp://hdl.handle.net/10198/20803
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevier
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectLigninpt_PT
dc.subjectColloidal particlespt_PT
dc.subjectScreening designpt_PT
dc.subjectProcess variables effects
dc.subjectPickering stabilizers
dc.titleDevelopment of colloidal lignin particles through particle design strategies and screening of their Pickering stabilizing potentialpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.titleColloids and Surfaces A-Physicochemical and Engineering Aspectspt_PT
person.familyNameColucci
person.familyNameSantamaria-Echart
person.familyNameTeixeira
person.familyNameBarreiro
person.givenNameGiovana
person.givenNameArantzazu
person.givenNameLiandra Gracher
person.givenNameFilomena
person.identifier.ciencia-id7C17-EC19-5F05
person.identifier.ciencia-id0C17-1E1F-2621
person.identifier.ciencia-id3910-3CB3-F50C
person.identifier.ciencia-id3418-47D5-5746
person.identifier.orcid0000-0002-8715-5843
person.identifier.orcid0000-0003-0107-7301
person.identifier.orcid0000-0003-1385-2037
person.identifier.orcid0000-0002-6844-333X
person.identifier.ridL-9802-2014
person.identifier.scopus-author-id56725697700
person.identifier.scopus-author-id57188719717
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication83d03823-c1ee-4787-a3a7-0d7f7046579e
relation.isAuthorOfPublicationeb945e05-928f-45cb-ac27-04b4159ae31a
relation.isAuthorOfPublication881dcc79-5c3a-4662-915a-6b1ec995e2de
relation.isAuthorOfPublication0391987c-ba90-488b-839a-153447ce1f0f
relation.isAuthorOfPublication.latestForDiscovery83d03823-c1ee-4787-a3a7-0d7f7046579e

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
Development of colloidal lignin particles.pdf
Size:
7.54 MB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.75 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

CIMO - Artigos em Revistas Indexados à WoS/Scopus