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Electrochemical and structural studies of nickel (II) Schiff base complexes derived from salicylaldehyde. Structural effects of bridge substituents on the stabilisation of the +3 oxidation state

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The oxidative chemistry of three Ni(II) complexes with Schiff base ligands derived from salicylaldehyde and diamines with different steric demands, N,N9-2-methylpropane-2,3-diyl-bis(salicylideneiminate)nickel(II) (1), N,N9-1,2-cyclohexyl-1,2-dyil-bis(salicylideneiminate)- nickel(II) (2) and N,N9-2,3-dimethylbutane-2,3-diyl-bis(salicylideneiminate)nickel(II) (3), was studied by cyclic voltammetry and chronoamperometry in N,N9-dimethylformamide and (CH3)2SO.

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Santos, I.C.; Vilas-Boas, Miguel; Piedade, M.F.M.; Freire, C.; Duarte, M.T.; Castro, B. (2000). Electrochemical and structural studies of nickel (II) Schiff base complexes derived from salicylaldehyde. Structural effects of bridge substituents on the stabilisation of the +3 oxidation state. Polyhedron. ISSN 0277-5387. 19:6, p. 655-664

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