Publicação
Carbon nanofibers prepared from ldpe for catalytic wet peroxide oxidation of paracetamol
| dc.contributor.author | Roman, Fernanda | |
| dc.contributor.author | Lopes, Jéssica Paula Marim | |
| dc.contributor.author | Díaz de Tuesta, Jose Luis | |
| dc.contributor.author | Silva, Adrián | |
| dc.contributor.author | Faria, Joaquim | |
| dc.contributor.author | Gomes, Helder | |
| dc.date.accessioned | 2021-10-28T15:22:38Z | |
| dc.date.available | 2021-10-28T15:22:38Z | |
| dc.date.issued | 2021 | |
| dc.description.abstract | Plastic solid waste (PSW) is a strong concern, as there is still a great fraction being sent to landfills (around 25% in EU), mainly plastic used for packaging purposes, such as low- density polyethylene (LDPE). The high content of elemental carbon in plastics (for example, LDPE consists of 85.6% of carbon) makes them alternative precursors for synthesis of carbon-based materials, such as carbon nanotubes and nanofibers (CNTs and CNFs, respectively). On the other hand, catalytic wet peroxide oxidation (CWPO) is a wastewater treatment process that uses hydrogen peroxide to generate strong oxidizing species, hydroxyl radicals, through the action of a suitable catalyst, commonly composed by a metal phase. More recently, metal-free catalysts are the trend on CWPO, as they avoid a series of issues, such as metal leaching and catalyst deactivation. Purified CNTs and CNFs fall in the category of metal-free materials. Thus, in this work, CNFs were synthesized from LDPE, used as carbon source. The obtained CNFs were purified to remove the metal particles from its structure, and both pristine and purified catalysts were tested in the CWPO of paracetamol (PCM), considered as model micropollutant, to compare their activity towards the removal of pollutant, total organic carbon (TOC) and efficiency of hydrogen peroxide consumption. | pt_PT |
| dc.description.sponsorship | This work was financially supported by project “PLASTIC_TO_FUEL&MAT – Upcycling Waste Plastics into Fuel and Carbon Nanomaterials” (PTDC/EQUEQU/ 31439/2017), Base Funding - UIDB/50020/2020 of the Associate Laboratory LSRE-LCM - funded by national funds through FCT/MCTES (PIDDAC), and CIMO (UIDB/00690/2020) through FEDER under Program PT2020. Fernanda F. Roman acknowledges the national funding by FCT through the individual research grant SFRH/BD/143224/2019. | pt_PT |
| dc.description.version | info:eu-repo/semantics/publishedVersion | pt_PT |
| dc.identifier.citation | Roman, Fernanda; Lopes, Jéssica P.M.; Díaz de Tuesta, Jose Luis; Silva, Adrián; Faria, Joaquim L.; Gomes, Helder (2021). Carbon nanofibers prepared from ldpe for catalytic wet peroxide oxidation of paracetamol. In VI Congresso Ibero-Americano de Empreendedorismo, Energia, Meio Ambiente e Tecnologia: Livro de Resumos. Bragança: Instituto Politécnico. ISBN 978-972-745-285-9 | pt_PT |
| dc.identifier.isbn | 978-972-745-285-9 | |
| dc.identifier.uri | http://hdl.handle.net/10198/24123 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.publisher | Instituto Politécnico de Bragança | pt_PT |
| dc.relation | Upcycling Waste Plastics into Fuel and Carbon Nanomaterials | |
| dc.relation | Laboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials | |
| dc.relation | Mountain Research Center - UIDB/00690/2020 | |
| dc.relation | Amphiphilic carbon-based materials for one-pot desulfurization and denitrogenation of liquid fuels | |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt_PT |
| dc.subject | Carbon nanotubes | pt_PT |
| dc.subject | Catalytic wet peroxide oxidation | pt_PT |
| dc.subject | Metal-free material | pt_PT |
| dc.subject | Paracetamol | pt_PT |
| dc.title | Carbon nanofibers prepared from ldpe for catalytic wet peroxide oxidation of paracetamol | pt_PT |
| dc.type | conference object | |
| dspace.entity.type | Publication | |
| oaire.awardNumber | PTDC/EQU-EQU/31439/2017 | |
| oaire.awardNumber | UIDB/50020/2020 | |
| oaire.awardNumber | UIDB/00690/2020 | |
| oaire.awardNumber | SFRH/BD/143224/2019 | |
| oaire.awardTitle | Upcycling Waste Plastics into Fuel and Carbon Nanomaterials | |
| oaire.awardTitle | Laboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials | |
| oaire.awardTitle | Mountain Research Center - UIDB/00690/2020 | |
| oaire.awardTitle | Amphiphilic carbon-based materials for one-pot desulfurization and denitrogenation of liquid fuels | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/9471 - RIDTI/PTDC%2FEQU-EQU%2F31439%2F2017/PT | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50020%2F2020/PT | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00690%2F2020/PT | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/POR_NORTE/SFRH%2FBD%2F143224%2F2019/PT | |
| oaire.citation.title | VI Congresso Ibero-Americano de Empreendedorismo, Energia, Meio Ambiente e Tecnologia | pt_PT |
| oaire.fundingStream | 9471 - RIDTI | |
| oaire.fundingStream | 6817 - DCRRNI ID | |
| oaire.fundingStream | 6817 - DCRRNI ID | |
| oaire.fundingStream | POR_NORTE | |
| person.familyName | Roman | |
| person.familyName | Díaz de Tuesta | |
| person.familyName | Gomes | |
| person.givenName | Fernanda F. | |
| person.givenName | Jose Luis | |
| person.givenName | Helder T. | |
| person.identifier.ciencia-id | EE1B-DAA7-D0BD | |
| person.identifier.ciencia-id | 7A1F-022B-7DBF | |
| person.identifier.ciencia-id | 6218-1E19-13EE | |
| person.identifier.orcid | 0000-0001-5360-5298 | |
| person.identifier.orcid | 0000-0003-2408-087X | |
| person.identifier.orcid | 0000-0001-6898-2408 | |
| person.identifier.rid | D-9785-2017 | |
| person.identifier.scopus-author-id | 55755821600 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | conferenceObject | pt_PT |
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