Publicação
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes
| dc.contributor.author | Karimi, Mohsen | |
| dc.contributor.author | Ferreira, Alexandre | |
| dc.contributor.author | Rodrigues, Alírio | |
| dc.contributor.author | Nouar, Farid | |
| dc.contributor.author | Serre, Christian | |
| dc.contributor.author | Silva, José A.C. | |
| dc.date.accessioned | 2023-01-20T16:03:27Z | |
| dc.date.available | 2023-01-20T16:03:27Z | |
| dc.date.issued | 2023 | |
| dc.description.abstract | The microporous bioderived Al dicarboxylate MIL-160(Al) MOF in its shaped form has been evaluated as a candidate for biogas upgrading (BU) and/or carbon capture and storage (CCS) by studying adsorption isotherms of CO2, CH4, and N2 at 313, 343, and 373 K until 8 bar. The isotherms disclosed the following loading capacities: 4.2 (CO2), 2.07 (CH4), and 0.69 (N2) mol/kg at 5.8 bar and 313 K, which fitted with the dual-site Langmuir model. The linear-driving-force coefficients (LDFs) for CO2 and CH4 calculated from uptake rate experiments are in the order of 0.021-0.096 and 0.041-0.165 s-1 at 313 K between 0.11 and 2.76 bar, respectively. The Response Surface Methodology (RSM) was also applied to maximize the selectivity for mixtures CO2/CH4 and CO2/N2 with interest for BU or CCS. Breakthrough curve experiments with mixtures CO2/CH4 and CO2/N2 at the optimum selectivity conditions were developed and simulated using ASPEN Adsorption. This work clearly demonstrates the potential of MIL-160(Al) to be used in BU and/or CCS-related applications. | pt_PT |
| dc.description.version | info:eu-repo/semantics/publishedVersion | pt_PT |
| dc.identifier.citation | Karimi, Mohsen; Ferreira, Alexandre; Rodrigues, Alírio; Nouar, Farid; Serre, Christian; Silva, José A.C. (2023). MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes. Industrial & Engineering Chemistry Research. ISSN 0888-5885. 62:12, p. 5216-5229 | pt_PT |
| dc.identifier.doi | 10.1021/acs.iecr.2c04150 | |
| dc.identifier.issn | 0888-5885 | |
| dc.identifier.uri | http://hdl.handle.net/10198/26621 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.publisher | American Chemical Society | pt_PT |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt_PT |
| dc.subject | Metal-organic frameworks | pt_PT |
| dc.subject | Molecular simulation | pt_PT |
| dc.subject | Gas-adsorption | pt_PT |
| dc.subject | Carbon capture | pt_PT |
| dc.subject | Separation | pt_PT |
| dc.subject | Water | |
| dc.subject | Performance | |
| dc.subject | Design | |
| dc.subject | CH4 | |
| dc.subject | Adsorbents | |
| dc.subject | Separation | |
| dc.title | MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.title | Industrial & Engineering Chemistry Research | pt_PT |
| person.familyName | Silva | |
| person.givenName | José A.C. | |
| person.identifier.ciencia-id | C11B-F5CF-7C78 | |
| person.identifier.orcid | 0000-0003-1778-3833 | |
| person.identifier.scopus-author-id | 7403023684 | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | article | pt_PT |
| relation.isAuthorOfPublication | 16366ede-a7d6-45ff-a8c9-eff9bdde35c7 | |
| relation.isAuthorOfPublication.latestForDiscovery | 16366ede-a7d6-45ff-a8c9-eff9bdde35c7 |