Repository logo
 
Publication

Phase equilibrium data and modeling of ethylic biodiesel, with application to a non-edible vegetable oil

2017Journal article Open access
Simple item page
dc.contributor.authorMuhammad, Fahad
dc.contributor.authorOliveira, Mariana B.
dc.contributor.authorPignat, Patrice
dc.contributor.authorJaubert, Jean-Noël
dc.contributor.authorPinho, Simão
dc.contributor.authorConiglio, Lucie
dc.date.accessioned2018-01-31T10:00:00Z
dc.date.accessioned2018-01-31T15:40:33Z
dc.date.available2018-01-31T10:00:00Z
dc.date.available2018-01-31T15:40:33Z
dc.date.issued2017
dc.description.abstractContributing to extending the knowledge for the design and operation of biodiesel production processes, isobaric PTxy vapor-liquid equilibria data of ethanol + ethyl hexanoate, 1-pentanol + ethyl hexanoate and 1-pentanol + ethyl octanoate at two different pressures are reported for the first time. Consistency tests were applied to attest the quality of the collected data, for these especially complex measurements. Besides that, vapor pressures of the pure ethyl esters have also been measured. For modeling purposes, the Lyngby and Dortmund UNIFAC variants were used to predict the VLE phase diagrams. Generally, the predictions are of very good quality, being the UNIFAC-Do (Dortmund) better, as the deviations in temperature and vapor compositions are always lower to 1.0 K and 0.020, respectively. Checking for the viability for extrapolations in pressure, CPA EoS was also applied to the modeling of the experimental data with very good results. Finally, aiming at examining the model capabilities to describe multicomponent systems, VLE measurements involving two alcohols and the fatty acid ethyl ester mixture obtained from non-edible vegetable oil have been carried out showing the good performance of the predictive models.en_EN
dc.description.sponsorshipThis work was developed in the scope of the Projects POCI-01- 0145-FEDER-006984 – Associate Laboratory LSRE-LCM and POCI- 01-0145-FEDER-007679 – CICECO-Aveiro Institute of Materials (FCT Ref. UID/CTM /50011/2013), funded by FEDER (European Union) through COMPETE2020 – Programa Operacional Competitividade e Internacionalização (POCI) – and by national funds through FCT (Portugal) – Fundação para a Ciência e a Tecnologia. Also, the authors express their acknowledgment to Frédéric Roze from Université de Lorraine – ENSIC (France) for his technical support during the work.
dc.description.versioninfo:eu-repo/semantics/publishedVersionen_EN
dc.identifier.citationMuhammad, Fahad; Oliveira, Mariana B.; Pignat, Patrice; Jaubert, Jean Noël; Pinho, Simão P.; Coniglio, Lucie (2017). Phase equilibrium data and modeling of ethylic biodiesel, with application to a non-edible vegetable oil. Fuel. ISSN 0016-2361. 203, p. 633-641en_EN
dc.identifier.doi10.1016/j.fuel.2017.05.007en_EN
dc.identifier.issn0016-2361
dc.identifier.urihttp://hdl.handle.net/10198/15362
dc.language.isoeng
dc.peerreviewedyesen_EN
dc.subjectBiodieselen_EN
dc.subjectConsistencyen_EN
dc.subjectCPAen_EN
dc.subjectNEVOen_EN
dc.subjectUNIFACen_EN
dc.subjectVapor–liquid equilibriumen_EN
dc.titlePhase equilibrium data and modeling of ethylic biodiesel, with application to a non-edible vegetable oilen_EN
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FCTM%2F50011%2F2013/PT
oaire.fundingStream5876
person.familyNamePinho
person.givenNameSimão
person.identifier810882
person.identifier.ciencia-id481D-73AD-8D0F
person.identifier.orcid0000-0002-9211-857X
person.identifier.ridD-4148-2013
person.identifier.scopus-author-id7003570175
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccessen_EN
rcaap.typearticleen_EN
relation.isAuthorOfPublication8ef7789a-34f3-4915-a666-4efe26272a30
relation.isAuthorOfPublication.latestForDiscovery8ef7789a-34f3-4915-a666-4efe26272a30
relation.isProjectOfPublicationad4b6226-d720-43f4-b75d-b2188a302a4e
relation.isProjectOfPublication.latestForDiscoveryad4b6226-d720-43f4-b75d-b2188a302a4e

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
25.pdf
Size:
949.89 KB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.75 KB
Format:
Plain Text
Description:
Download

Collections

CIMO - Artigos em Revistas Indexados à WoS/Scopus