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Calculation of CLD using population balance equations of generating functions: linear and non-linear ideal controlled radical polymerization

2010Journal article Restricted access
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dc.contributor.authorDias, Rolando
dc.contributor.authorCosta, Mário Rui
dc.date.accessioned2010-08-30T11:02:21Z
dc.date.available2010-08-30T11:02:21Z
dc.date.issued2010
dc.description.abstractPopulation balance equations in terms of generating functions (GF) are used to predict chain length distributions (CLD) of linear and non-linear ideal controlled radical polymerization (CRP) systems. It is here shown that under simplified conditions analytical solutions for the CLD can be found and moreover the fundamental CLD derived by H. Tobita in 2006 is a limiting case of the more general solutions here presented. In order to deal with more complex CRP systems, solutions based upon the numerical inversion of GF are presented. These studies are also extended to the non-linear CRP of vinyl/divinyl monomers where multimodal CLDs are predicted to occur.por
dc.description.sponsorshipFundação para a Ciência e a Tecnologia (FCT), Ministry of Science and Technology of Portugal, European Community through FEDER, Project PTDC/EQU-EQU/098150/2008 (COMPETE-QCA III), Marie Curie Initial Training Network Nanopoly (ITN-GA-2009-238700)por
dc.description.sponsorshipFundação para a Ciência e a Tecnologia (FCT), Ministry of Science and Technology of Portugal, European Community through FEDER, Project PTDC/EQU-EQU/098150/2008 (COMPETE-QCA III), Marie Curie Initial Training Network Nanopoly (ITN-GA-2009-238700)
dc.identifier.citationDias; Rolando, Costa; Mário (2010). Calculation of CLD using population balance equations of generating functions: linear and non-linear ideal controlled radical polymerization. Macromolecular Theory and Simulations. ISSN 1022-1344.por
dc.identifier.doi10.1002/mats.201000008
dc.identifier.issn1022-1344
dc.identifier.urihttp://hdl.handle.net/10198/2571
dc.language.isoengpor
dc.publisherWILEY-VCHpor
dc.relationMolecular Engineering, Synthesis and Testing of Water Compatible Smart Polymers
dc.subjectControlled radical polymerizationpor
dc.subjectCross-linkingpor
dc.subjectGenerating functionpor
dc.subjectMolecular weight distributionpor
dc.subjectPopulation balancespor
dc.titleCalculation of CLD using population balance equations of generating functions: linear and non-linear ideal controlled radical polymerizationpor
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleMolecular Engineering, Synthesis and Testing of Water Compatible Smart Polymers
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876-PPCDTI/PTDC%2FEQU-EQU%2F098150%2F2008/PT
oaire.citation.issue19por
oaire.citation.startPageNApor
oaire.citation.titleMacromolecular Theory and Simulationspor
oaire.fundingStream5876-PPCDTI
person.familyNameDias
person.givenNameRolando
person.identifier.ciencia-id8417-4D84-973B
person.identifier.orcid0000-0001-7369-382X
person.identifier.ridM-8552-2013
person.identifier.scopus-author-id7102885104
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspor
rcaap.typearticlepor
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relation.isAuthorOfPublication.latestForDiscoveryd7109687-6adf-4268-a462-8d1a2e2c01cb
relation.isProjectOfPublication4d9be255-5948-4f8c-a746-b2edc235989f
relation.isProjectOfPublication.latestForDiscovery4d9be255-5948-4f8c-a746-b2edc235989f

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