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Advances in waterborne polyurethane and polyurethane-urea dispersions and their eco-friendly derivatives: a review

2021Journal article Open access
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dc.contributor.authorSantamaria-Echart, Arantzazu
dc.contributor.authorFernandes, Isabel P.
dc.contributor.authorBarreiro, M.F.
dc.contributor.authorCorcuera, Maria Angeles
dc.contributor.authorEceiza, Arantaxa
dc.date.accessioned2018-02-19T10:00:00Z
dc.date.accessioned2021-12-02T16:31:55Z
dc.date.available2018-01-19T10:00:00Z
dc.date.available2021-12-02T16:31:55Z
dc.date.issued2021
dc.description.abstractPolyurethanes and polyurethane-ureas, particularly their water-based dispersions, have gained relevance as an extremely versatile area based on environmentally friendly approaches. The evolution of their synthesis methods, and the nature of the reactants (or compounds involved in the process) towards increasingly sustainable pathways, has positioned these dispersions as a relevant and essential product for diverse application frameworks. Therefore, in this work, it is intended to show the progress in the field of polyurethane and polyurethane-urea dispersions over decades, since their initial synthesis approaches. Thus, the review covers from the basic concepts of polyure-thane chemistry to the evolution of the dispersion’s preparation strategies. Moreover, an analysis of the recent trends of using renewable reactants and enhanced green strategies, including the current legislation, directed to limit the toxicity and potentiate the sustainability of dispersions, is described. The review also highlights the strengths of the dispersions added with diverse renewable additives, namely, cellulose, starch or chitosan, providing some noteworthy results. Similarly, dispersion’s potential to be processed by diverse methods is shown, evidencing, with different examples, their suitability in a variety of scenarios, outstanding their versatility even for high requirement applications.en_EN
dc.description.sponsorshipThis research was funded by the University of the Basque Country (UPV/EHU) (GIU18/216 Research Group), the Spanish Ministry of Science, Innovation and Universities and European Union (MICINN/EU/FEDER) (MAT2016-76294-R and PID2019-105090RB-I00). Also, the Foundation for Science and Technology (FCT, Portugal) funded by financial support by national funds FCT/MCTES to CIMO (UIDB/00690/2020). National funding by FCT- Foundation for Science and Technology, through the institutional scientific employment program-contract with I.F.
dc.description.versioninfo:eu-repo/semantics/publishedVersionen_EN
dc.identifier.citationSantamaria-Echart, Arantzazu; Fernandes, Isabel; Barreiro, Filomena; Corcuera, Maria Angeles; Eceiza, Arantxa (2021). Advances in waterborne polyurethane and polyurethane-urea dispersions and their eco-friendly derivatives: a review. Polymers. ISSN 2073-4360. 13:3, p. 1-32en_EN
dc.identifier.doi10.3390/polym13030409en_EN
dc.identifier.urihttp://hdl.handle.net/10198/24445
dc.language.isoeng
dc.peerreviewedyesen_EN
dc.relationMountain Research Center
dc.subjectAlternative internal emulsifiersen_EN
dc.subjectApplicationsen_EN
dc.subjectLegislationen_EN
dc.subjectMaterials’ propertiesen_EN
dc.subjectPolyurethane and polyurethane-urea dispersionsen_EN
dc.subjectProcessing methodsen_EN
dc.subjectRenewable additivesen_EN
dc.subjectSustainable strategiesen_EN
dc.subjectSynthesis methodsen_EN
dc.titleAdvances in waterborne polyurethane and polyurethane-urea dispersions and their eco-friendly derivatives: a reviewen_EN
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleMountain Research Center
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00690%2F2020/PT
oaire.fundingStream6817 - DCRRNI ID
person.familyNameSantamaria-Echart
person.familyNameFernandes
person.familyNameBarreiro
person.givenNameArantzazu
person.givenNameIsabel P.
person.givenNameFilomena
person.identifier.ciencia-id0C17-1E1F-2621
person.identifier.ciencia-id4D1C-441F-C7F0
person.identifier.ciencia-id3418-47D5-5746
person.identifier.orcid0000-0003-0107-7301
person.identifier.orcid0000-0002-0069-4503
person.identifier.orcid0000-0002-6844-333X
person.identifier.ridL-1552-2016
person.identifier.ridL-9802-2014
person.identifier.scopus-author-id56725697700
person.identifier.scopus-author-id26323585300
person.identifier.scopus-author-id57188719717
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccessen_EN
rcaap.typearticleen_EN
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relation.isAuthorOfPublicationaa1919bb-c35d-4abb-a137-10d998ad4eca
relation.isAuthorOfPublication0391987c-ba90-488b-839a-153447ce1f0f
relation.isAuthorOfPublication.latestForDiscoveryeb945e05-928f-45cb-ac27-04b4159ae31a
relation.isProjectOfPublication29718e93-4989-42bb-bcbc-4daff3870b25
relation.isProjectOfPublication.latestForDiscovery29718e93-4989-42bb-bcbc-4daff3870b25

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