Development of Polyethersulphone Mixed Matrix Zeolite Membranes Functionalized with Ionic Liquids and Deep Eutectic Solvents for CO2 Separation

Cardoso, Jonathan; Lin, Zhi; Brito, Paulo; Ferreira, Licínio

http://hdl.handle.net/10198/35998

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Resumo(s)

Mixed matrix membranes (MMM) combine the flexibility of polymers and the strength and durability presented by inorganic solids. In an economically point of view, the advantages of membrane separation are low capital investment and space requirements, high process flexibility and lower energy consumption, helping for a more cost-effective separation process and providing a high separation degree. The molecular sieves based on nano-sized silicoaluminophosphates (SAPO) appear as one of the main materials in MMM for gas separation because the pore size of chabazite (CHA) (0.38 nm) is near the kinetic diameter of gases like H2 (0.29 nm), CO2 (0.33 nm), N2 (0.36 nm), CO (0.37 nm), CH4 (0.38 nm) and reduced crystal size improves the dispersion and decreases interfacial defects. Doping SAPO-34 are intended to increase the potential of these solids. The use of isomorphic substitution by transition metals (Fe, Ni, Co, Mn), results in materials with different acidity that differ from the original SAPO in interactions with other compounds. Besides, the addition of ionic liquids (IL) or Deep Eutectic Solvents (DES) with high affinity and selectivity to CO2, onto the particle surface and then dispersing it in a polymer membrane can enhance the separation characteristics, resulting in better permeation and selectivity properties.

Palavras-chave

Mixed matrix membranes CO2 separation Ionic liquids Deep eutectic solvent Permeability Selectivity

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http://hdl.handle.net/10198/35998

Citação

Cardoso, Jonathan; Lin, Zhi; Brito, Paulo; Ferreira, Licínio (2023). Development of Polyethersulphone Mixed Matrix Zeolite Membranes Functionalized with Ionic Liquids and Deep Eutectic Solvents for CO2 Separation. In 9th International Conference on Energy and Environment Research, ICEER 2022. Cham: Springer Nature. p. 381-391. ISBN 978-303143558-4