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Techno-Economic and Energy Assessment of the Pressure Swing Adsorption Process for CO2Capture from Flue Gas Using Shaped MOF MIL-160(Al): Bridging Experimental Results into Industrial Implementation

2026Artigo científico Acesso aberto
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datacite.subject.fosCiências Naturais::Ciências Químicas
datacite.subject.fosCiências Naturais::Ciências da Terra e do Ambiente
datacite.subject.sdg13:Ação Climática
datacite.subject.sdg09:Indústria, Inovação e Infraestruturas
datacite.subject.sdg07:Energias Renováveis e Acessíveis
datacite.subject.sdg04:Educação de Qualidade
dc.contributor.authorKarimi, Mohsen
dc.contributor.authorShirzad, Mohammad
dc.contributor.authorSiqueira, Rafael M.
dc.contributor.authorFerreira, Alexandre
dc.contributor.authorSilva, José A.C.
dc.contributor.authorRodrigues, Alírio E.
dc.date.accessioned2026-03-18T11:55:02Z
dc.date.available2026-03-18T11:55:02Z
dc.date.issued2026
dc.description.abstractThis work provides an integrated techno-economic and energy assessment of vacuum pressure swing adsorption (VPSA) for postcombustion CO2 capture, bridging laboratory-scale validation with industrial-scale design. The shaped MOF MIL-160(Al) was evaluated through 19 dynamic PSA experiments, which clarified the distinct roles of purge and rinse steps in determining the separation efficiency. The validated process model reliably captured cyclic steady-state dynamics and was extended to simulate 31 industrial VPSA configurations. The results demonstrated that as purge flow increased from 500 to 7.5 & times; 103 L/min, CO2 purity reduced from 91% to 82%, but CO2 recovery increased from 65% to 96%, which corresponds to an enhancement in energy consumption from 1589.2 to 1655 kWh. On the other hand, when rinse flow enhanced from 30 & times; 103 to 39 & times; 103 L/min, CO2 purity increased from 82% to 89%, while CO2 recovery reduced from 90% to 86% and energy consumption increased from 1573.5 to 1657.9 kWh. Techno-economic analysis estimated a total capital investment of $18.89 M and an annualized capital expenditure (CapEx) of $1.82 M & centerdot;yr-1, with operating costs dominated by electricity consumption and, to a lesser extent, labor cost. Overall, the findings prove that industrially viable deployment of MIL-160(Al)-based VPSA requires a combined focus on plant equipment lifetime and process-level energy optimization, thereby providing a clear roadmap for translating experimental performance into large-scale CO2 capture.eng
dc.description.sponsorshipThis work was supported by national funds through FCT/MCTES (PIDDAC): CIMO UID/00690/2025 (10.54499/UID/00690/2025) and UID/PRR/00690/2025 (10.54499/UID/PRR/00690/2025); SusTEC, LA/P/0007/2020 (DOI: 10.54499/LA/P/0007/2020). The authors also would like to acknowledge Christian Serre and Farid Nouar from Institut des Matériaux Poreux de Paris, ESPCI Paris, Ecole Normale Supérieure, PSL University, Paris, France, for providing the MOF MIL-160(Al) samples. They also recognize the scientific/industrial counseling provided by Padjam Polymer Development Co. (Private joint stock), Asaluyeh Port, Iran.
dc.identifier.citationKarimi, Mohsen; Shirzad, Mohammad; Siqueira, Rafael M.; Ferreira, Alexandre; Silva, Jose A. C.; Rodrigues Alirio E. (2026). Techno-Economic and Energy Assessment of the Pressure Swing Adsorption Process for CO2 Capture from Flue Gas Using Shaped MOF MIL-160(Al): Bridging Experimental Results into Industrial Implementation. Industrial e Engineering Chemistry Research. ISSN 0888-5885. 65:8, p. 4633-4647
dc.identifier.doi10.1021/acs.iecr.5c04931
dc.identifier.issn0888-5885
dc.identifier.issn1520-5045
dc.identifier.urihttp://hdl.handle.net/10198/36121
dc.language.isoeng
dc.peerreviewedyes
dc.publisherAmerican Chemical Society
dc.relationMountain Research Center
dc.relationAssociate Laboratory for Sustainability and Tecnology in Mountain Regions
dc.relation.ispartofIndustrial & Engineering Chemistry Research
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/
dc.subjectMetal-Organic Frameworks
dc.subjectCarbon-Dioxide Capture
dc.subjectAdsorbents
dc.titleTechno-Economic and Energy Assessment of the Pressure Swing Adsorption Process for CO2Capture from Flue Gas Using Shaped MOF MIL-160(Al): Bridging Experimental Results into Industrial Implementationeng
dc.typejournal article
dspace.entity.typePublication
oaire.awardNumberUID/00690/2025
oaire.awardNumberLA/P/0007/2020
oaire.awardTitleMountain Research Center
oaire.awardTitleAssociate Laboratory for Sustainability and Tecnology in Mountain Regions
oaire.awardURIhttp://hdl.handle.net/10198/35759
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0007%2F2020/PT
oaire.citation.endPage4647
oaire.citation.issue8
oaire.citation.startPage4633
oaire.citation.titleIndustrial & Engineering Chemistry Research
oaire.citation.volume65
oaire.fundingStreamCIMO
oaire.fundingStream6817 - DCRRNI ID
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85
person.familyNameSilva
person.givenNameJosé A.C.
person.identifier.ciencia-idC11B-F5CF-7C78
person.identifier.orcid0000-0003-1778-3833
person.identifier.scopus-author-id7403023684
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
relation.isAuthorOfPublication16366ede-a7d6-45ff-a8c9-eff9bdde35c7
relation.isAuthorOfPublication.latestForDiscovery16366ede-a7d6-45ff-a8c9-eff9bdde35c7
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