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Biobased additives as biodegradability enhancers with application in TPU-based footwear components

dc.contributor.authorFernandes, Isabel P.
dc.contributor.authorBarbosa, Mariana Martinho
dc.contributor.authorAmaral, Joana S.
dc.contributor.authorPinto, Vera
dc.contributor.authorRodrigues, José Luís
dc.contributor.authorFerreira, Maria José
dc.contributor.authorBarreiro, M.F.
dc.date.accessioned2016-05-09T13:59:37Z
dc.date.available2016-05-09T13:59:37Z
dc.date.issued2016
dc.description.abstractAmong the wide variety of materials employed in the manufacture of shoes, thermoplastic polyurethanes (TPUs) are one of the most widely used. Given its widespread use, and associated waste management problems, the development of more biodegradable and evironmentally compatible solutions is needed. In this work, a polyester-based TPU used in the footwear industry for outsoles production was modified by compounding with lignin, starch and cellulose at content of 4% (w/w). The biodegradability was evaluated by using agar plate tests with the fungi Aspergillus niger ATCC16404, the Gram-negative bacteria Pseudomonas aeruginosa ATCC9027 and an association of both (consortium), and soil tests at 37 °C and 58 °C. The obtained results evidenced a positive effect of the tested biobased additives, the most favourable results being registered with lignin. These results were corroborated by the structural modifications observed by FTIR analysis. Additionally, mechanical tests prove the suitability of using the lignin modified TPUs for footwear outsoles production.pt_PT
dc.identifier.citationFernandes, Isabel Patrícia; Barbosa, Mariana; Amaral, Joana Soares; Pinto, Vera; Rodrigues, José Luís; Ferreira, Maria José; Barreiro, M. F. (2016). Biobased additives as biodegradability enhancers with application in TPU-based footwear components. Journal of Renewable Materials. ISSN 2164-6325. 4:1, p.47-56.pt_PT
dc.identifier.doi10.7569/JRM.2015.634126pt_PT
dc.identifier.issn2164-6325
dc.identifier.urihttp://hdl.handle.net/10198/12924
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherScrivener Publishingpt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectThermoplastic polyurethanespt_PT
dc.subjectBiodegradablept_PT
dc.subjectNatural additivespt_PT
dc.subjectFootwearpt_PT
dc.titleBiobased additives as biodegradability enhancers with application in TPU-based footwear componentspt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FEQU%2F50020%2F2013/PT
oaire.citation.endPage56pt_PT
oaire.citation.startPage47pt_PT
oaire.citation.titleJournal of Renewable Materialspt_PT
oaire.citation.volume4 (1)pt_PT
oaire.fundingStream5876
person.familyNameFernandes
person.familyNameSoares Amaral
person.familyNameBarreiro
person.givenNameIsabel Patrícia
person.givenNameJoana Andrêa
person.givenNameFilomena
person.identifier.ciencia-id4D1C-441F-C7F0
person.identifier.ciencia-id5319-7DE8-BEDA
person.identifier.ciencia-id3418-47D5-5746
person.identifier.orcid0000-0002-0069-4503
person.identifier.orcid0000-0002-3648-7303
person.identifier.orcid0000-0002-6844-333X
person.identifier.ridL-1552-2016
person.identifier.ridL-9802-2014
person.identifier.scopus-author-id26323585300
person.identifier.scopus-author-id57188719717
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsrestrictedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationaa1919bb-c35d-4abb-a137-10d998ad4eca
relation.isAuthorOfPublication42be2cf4-adc4-4e7f-ac60-7aab515b38cd
relation.isAuthorOfPublication0391987c-ba90-488b-839a-153447ce1f0f
relation.isAuthorOfPublication.latestForDiscovery0391987c-ba90-488b-839a-153447ce1f0f
relation.isProjectOfPublication66ec3fc3-043e-4147-a64b-3d87442cc076
relation.isProjectOfPublication.latestForDiscovery66ec3fc3-043e-4147-a64b-3d87442cc076

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