CIMO - Artigos em Revistas Indexados à WoS/Scopus
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- Curcumin Nanoparticles as a Pigment of Polyamide Textiles: Influence of Conditions in the Exhaust Dyeing and Evaluation of Wastewater ToxicityPublication . Moraes, Katharina S.; Oliveira, Aline de; Ferreira, Bruna T. M.; Bona, Evandro; Carneiro, Jaqueline; Peron, Ana Paula; Fernandes, Marta; Zille, Andrea; Leimann, Fernanda V.; Aguiar, Catia R. Lange de; Silva, Márcia G. da; Ferreira, Alexandre J. S.; Vila, Nívea T.; Gonçalves, Odinei HessThe growing demand for eco-friendly and sustainable solutions in textile dyeing has attracted interest in natural dyes, since the synthetic counterparts may be potentially damaging to the environment and require the use of additives to efficiently bind them to the fibers. Curcumin, a natural dye derived from Curcuma longa L. rhizomes, has attracted attention due to its notable biological activity and vibrant yellow-orange hue; however, its direct application remains limited by challenges related to dye fixation and color fastness. This study aimed to evaluate the use of curcumin nanoparticles in the dyeing of polyamide 6.6, as well as to assess the toxicity level of the effluent generated during the exhaust dyeing process. Colloidally stable nanoparticles with average sizes of 454 and 419 nm were obtained with PVP (polyvinylpyrrolidone) and Poloxamer 407 as the polymeric stabilizer, respectively. A factorial 24-1 experimental design was implemented, showing a reduction in color intensity at higher dyeing temperatures, while acidic conditions enhanced dye uptake, leading to improved color depth. Two formulations were selected for a more detailed characterization. Regarding the wash currently used by the textile field, the scores found demonstrated that color did not change during washing. Excellent ratings were found in the rubbing and perspiration fastness and the ultraviolet protection factor for the textiles dyed with PVP and Poloxamer 407 stabilizers. The wastewater of the dyeing process under selected experimental conditions was evaluated with respect to the phytotoxicity, genotoxicity, and cytotoxicity in in vivo models. Based on the results, the wastewater samples analyzed may be environmentally safe.
- Enhancing single and multi-component adsorption efficiency of pharmaceutical emerging contaminants using bio waste-derived carbon materials and geopolymersPublication . Silva, Ana P. F.; Baldo, Arthur P.; Silva, Adriano S.; Natal, Ana Paula S.; Bezerra, Ana J.B.; Tuesta, Jose L. Diaz de; Marin, Pricila; Peres, José A.; Gomes, HelderWater contamination with pharmaceuticals like acetaminophen (ACT), sulfamethoxazole (SMX), and phenolic compounds such as gallic acid (GA), have become a global concern. These contaminants are persistent environmental pollutants that threaten aquatic life and human health. Adsorption is recognized as an efficient and low-cost solution to tackle water pollution. In this study, the efficiency of three adsorbents—activated carbon (AC), geopolymer (GP), and carbon nanotubes (CNT) prepared from solid wastes for the removal of ACT, SMX, and GA by adsorption is assessed. AC, GP and CNT are synthesized from real wastes to address solid waste management needs. Physisorption confirmed AC superior BET surface area (527 m2 g 1), followed by CNTs (66 m2 g 1) and GPs (30 m2 g 1), allowing to achieve the highest adsorption capacity: 126.8 mg g 1 for ACT, 54.9 mg g 1 for SMX, and 151.5 mg g 1 for GA, with respective breakthrough times of 314, 66, and 68 min. Kinetic and isotherm adsorption models are fitted for all pair pollutant-adsorbent reaching 33 equations to accurately predict adsorption process, concluding that pseudo-second-order kinetic and Freundlich model best fit experimental data, demonstrating a strong adsorbent-adsorbate affinity. The findings suggest that these sustainable materials offer promising solutions for treating contaminated water.
- Environmental Impact of Wastewater on Surface and Groundwater in Central AsiaPublication . Kalmakhanova, Marzhan S.; Kurtebayeva, Assel A.; Tleuova, Zhanna T.; Satybaldiev, Bagdat; Orynbayev, Seitzhan A.; Malakar, Arindam; Gomes, Helder; Snow, Daniel D.This review aims to increase attention on present water quality issues on Central Asia, finding gaps in the literature on ways to address treatment needs, and help ensure future use of Central Asia surface waters and groundwater for all beneficial uses. Central Asia is a landlocked region known for its harsh climatic conditions and scarce water resources, despite being home to some of the world's largest internal drainage basins. The available literature suggests that increasing salinity has rendered water unsuitable for irrigation and consumption; hazardous trace elements are found throughout Central Asia, most often associated with mining and industrial sources; and that legacy pesticides influence water quality, particularly in agriculturally influenced basins. This study also focuses on the effects of municipal and industrial wastewater discharge. Additionally, the impact of inadequately treated wastewater on water resources is analyzed through a review of available data and reports regarding surface and groundwater quantity and quality. Given the challenges of water scarcity and accessibility, the reuse of treated wastewater is becoming increasingly important, offering a valuable alternative that necessitates careful oversight to ensure public health, environmental sustainability, and water security. However, due to insufficient financial and technical resources, along with underdeveloped regulatory frameworks, many urban areas lack adequate wastewater treatment facilities, significantly constraining their safe and sustainable reuse. Proper management of wastewater effluent is critical, as it directly influences the quality of both surface and groundwater, which serve as key sources for drinking water and irrigation. Due to their persistent and biologically active nature even at trace levels, we discuss contaminants of emerging concern such as antibiotics, pharmaceuticals, and modern agrochemicals. This review thus highlights gaps in the literature reporting on impacts of wastewater inputs to water quality in Central Asia. It is recommended that future research and efforts should focus on exploring sustainable solutions for water quality management and pollution control to assure environmental sustainability and public health.
- Impacts of climate-induced drought on lake and reservoir biodiversity and ecosystem services: a reviewPublication . Sun, Xinyu; Armstrong, Margaret; Moradi, Amirmohammad; Bhattacharya, Ruchi; Geraldes, Ana Maria; Munthali, Elias; Grossart, Hans-Peter; Matsuzaki, Shin-Ichiro; Kangur, Külli; Dunalska, Julita; Stockwell, Jason; Borre, LisaIntensifying extreme droughts are altering lentic ecosystems and disrupting services provisioning. Unfortunately, drought research often lacks a holistic and intersectoral consideration of drought impacts, which can limit relevance of the insights for adaptive management. This literature review evaluated the current state of lake and reservoir extreme drought research in relation to biodiversity and three ecosystem services. The study findings demonstrated that few articles linked or discussed drought implications with one or more ecosystem services, instead focusing primarily on biodiversity. Drought effects on biodiversity varied among species and taxonomic groups. In the limited literature that included ecosystem service provisioning, droughts had a general negative effect. Drinking water supply can decrease and become more costly. Decreasing water flow and volume can reduce hydropower generation. Degraded water quality can also impact recreation. Future intersectoral collaborations and research on intensifying droughts should support adaptive management efforts in mitigating drought impacts.
- Impacts of soil humic acids on the presence of PPCPs in reclaimed waterPublication . Conde-González, J.E.; Hernandez Hernandez, Zulimar; Aguiar, V.; Vera, L.; Marrero, M.C.; Salvadó, V.; Peña-Méndez, E.M.A multidisciplinary approach investigates the interaction between selected PPCPs with diversified physicochemical propertiesand humic acids (HAs) extracted from Elliot and volcanic soils in reclaimed water (RW). Principal component analysis (PCA) reveals significant differences between the two HAs and how these differences affect PPCP-HA interaction which are characterized by UV spectroscopy. The sorption of PPCPs on either IHSS HA or CAN HA fit a pseudo-second-order kinetic reaction in RW, indicating that the adsorption rate was controlled by the diffusion of the PPCP, followed by adsorption on the HA surface. The sorption of each individual PPCP on both HAs was characterized by applying sorption isotherm models, showing that chemisorption is involved. Moreover, the simultaneous PPCP-HA interactions between the selected PPCPs and both HAs in RW (at different pHs) fitted Freundlich's model (R-2 > 0.9890), where, K-F values are 0.0003 and 0.085 for simultaneous adsorption on IHSS HA and CAN HA, respectively. The greater K-F value obtained for CAN HA suggests that the simultaneous PPCP adsorption is more favourable in this HA than in IHSS HA. Meanwhile, coexisting Ca2+ (>50 mM) in RW could inhibit the PPCP-HA interaction due to the aggregation of HAs. This study highlights the importance of the HA origin in the interaction with PPCPs in RW, which can affect the fate and transport of these pollutants and the associated environmental risk.
- Life cycle approach as a tool for assessing municipal biowaste treatment units: a systematic reviewPublication . Serafini, Lais Fabiana; Praça, Paulo; González-Andrés, Fernando; Gonçalves, ArturBiowaste is an increasingly relevant environmental issue worldwide, causing significant environmental, economic and social impacts. Effective strategies are crucial to mitigate impacts, maximising biowaste’s valorisation. This article presents a systematic literature review on using life cycle assessment (LCA) to evaluate municipal biowaste treatment facilities. The primary objective was to analyse how LCA is applied to assess the environmental efficiency of mechanical and biological treatment involving composting and anaerobic digestion (AD)-based systems. The article addressed the methodological heterogeneity across previous LCA studies, identifying critical gaps and challenges regarding standardisation and result comparability. It underscores the importance of accurately considering environmental indicators and emission factors, as these significantly affect overall LCA outcomes. Results show that most publications focus on Europe and Asia, highlighting a research gap in regions like Africa. The organic fraction municipal solid waste is the predominant feedstock, and 1 tonne of biowaste was the frequently used functional unit, reflecting the upstream impacts of waste. The most recurrent system boundary was the cradle-to-grave, offering a comprehensive analysis as it covers all stages of biowaste treatment from collection to disposal. The studies highlight the environmental benefits of AD-based systems through energy production compensations, particularly in reducing global warming potential, compared with other treatment operations such as landfills. While replacing mineral fertilisers with digestate and compost is very well discussed, it raises concerns about heavy metal content and nutrient availability. Therefore, selective collection of organic waste is crucial to improve compost quality and AD efficiency, though it increases transportation costs.
- Pharmaceuticals in the Douro basin: Occurrence, distribution, and ecological riskPublication . Voznakova, Alena; Geraldes, Ana Maria; Canle, MoisésThis study assesses water quality in the Portuguese section of the Douro River basin (Bragan & ccedil;a region, NE Portugal) by evaluating the presence and potential impact of pharmaceutical contaminants (PhCs), classified as contaminants of emerging concern (CECs). A set of 65 pharmaceuticals was investigated for their occurrence and ecological and health impact. The extent of contamination by these compounds, and its possible effects on the aquatic ecosystem was analyzed and discussed. Additionally, the accumulation of these pharmaceuticals in sediments is investigated, providing a more comprehensive understanding of their distribution and persistence in the environment. Out of these 65 CECs, 23 were found in water and 10 in sediments. The most abundant correspond to acetaminophen, diclofenac and ibuprofen. The data obtained are used in this paper to develop an environmental indicator system, which serves as a valuable tool for assessing ecosystem health and water quality. This system provides key information to support decision-making regarding environmental management and conservation. Ultimately, this integrated approach aims to enhance the understanding and protection of water resources in the Bragan & ccedil;a region and beyond.
- Physicochemical Characterisation of Olive Mill Wastewaters Based on Extraction Methods and Filtration LevelsPublication . Afonso, Inês Santos ; Duarte, Cristina; Afonso, Maria João A.P.S.; Ribeiro, António E.; Amaral, Joana S.; Sousa, Patrícia C.; Lima, Rui A.; Ribeiro, João E.Olive mill wastewaters (OMWW) generated during olive oil extraction represent a significant environmental challenge due to their high organic matter content, acidic pH, phenolic content, and toxicity. Their composition varies widely depending on the extraction method and remains difficult to treat, particularly for small-scale producers lacking access to complex infrastructure. This study evaluates the combined effect of the extraction system (traditional vs. three-phase continuous) and filtration level (single vs. double) on the physicochemical and biological properties of OMWW. The methodologies employed included the analysis of water content, density, fatty acid composition, acidity, pH, total solids, chemical and biochemical oxygen demand, and biodegradability. The results indicate that traditional systems consistently produced OMWW with higher organic matter and phenolic loads, while filtration moderately reduced antioxidant potential and acidity, especially in traditional systems. The use of simple, low-cost filtration materials proved effective in improving effluent clarity and could serve as a practical pre-treatment option. This approach offers an accessible strategy for small producers aiming to valorise OMWW or reduce environmental impact. However, the study was conducted at the laboratory scale, and the long-term behaviour of filtered OMWW under real operating conditions remains to be evaluated.
- Sewage Sludge Provided Nitrogen To Maize (Zea Mays L.) Very Rapidly, Demonstrating a High Short-Term Net Mineralization RatePublication . Dimande, Paulo; Arrobas, Margarida; Rodrigues, Manuel ÂngeloThis study aims to evaluate the potential of sewage sludge as a sustainable alternative to traditional farmyard manures, considering the limited availability of such resources in many regions specializing in crop production. This study compared the application of sewage sludge (SS) and cow manure (CM) at equivalent nitrogen (N) rates in silage maize (Zea mays L.) cultivation over two growing seasons. Organic amendments were applied at rates of 50 (SS50, CM50), 100 (SS100, CM100), and 200 (SS200, CM200) kg ha(-)(1) of N, alongside an unfertilized control (N0), with three replicates per treatment in a completely randomized design. Dry matter yield (DMY) increased significantly with the applied dose but showed no significant differences between amendments. N availability indices, including the pre-side-dress soil nitrate test, leaf N concentration, and stalk nitrate test, revealed higher N availability from sewage sludge compared to cow manure at equivalent application rates. Apparent N recovery (ANR) by the end of the second growing season was 99.8%, 90.8%, and 74.5% for SS50, SS100, and SS200, respectively, and 76.7%, 75.4%, and 50.5% for CM50, CM100, and CM200, respectively. The rapid mineralization of sewage sludge likely results from its low carbon (C)/N ratio and the absence of lignin and other low-energy organic compounds, which are less metabolically accessible to soil microorganisms. These properties position sewage sludge as an intermediate between conventional organic compost and mineral fertilizers, making it particularly suitable for cropping systems requiring high short-term N availability.
- Use of Permeable Reactive Barriers in the Removal of ACT and DCF from Effluents of Wastewater Treatment PlantsPublication . Kalmakhanova, Marzhan S.; Khabashova, Aidana U.; Nurlybayeva, Aisha N.; Orynbayev, Seitzhan A.; Gomes, Helder; Snow, Daniel D.Pharmaceuticals such as paracetamol and diclofenac (DCF) are among the most extensively consumed drugs worldwide and are continuously released into municipal and hospital wastewater due to incomplete human metabolism. Their persistent presence in aquatic environments, typically ranging from ng/L to µg/L, raises concerns due to endocrine disruption, chronic toxicity, and the promotion of antimicrobial resistance. Conventional wastewater treatment plants (WWTPs) remove 70–90% of ACT but less than 30% of DCF, primarily because these systems were not designed to target low-concentration, recalcitrant micropollutants. As a result, pharmaceuticals frequently pass into treated effluents, highlighting the need for advanced, sustainable, and passive treatment solutions. Permeable reactive barriers (PRBs) have emerged as a promising technology for the interception and removal of pharmaceuticals from both wastewater treatment plant effluents and groundwater. This review provides a comprehensive assessment of ACT and DCF occurrence, environmental behavior, and ecotoxicological risks, followed by a detailed evaluation of PRB performance using advanced reactive media such as geopolymers, activated carbon, carbon nanotubes, and hybrid composites. Reported removal efficiencies exceed 90% for ACT and 70–95% for DCF, depending on media composition and operating conditions. The primary removal mechanisms include adsorption, ion exchange, π–π interactions, hydrogen bonding, and redox transformation. The novelty of this review lies in systematically synthesizing recent laboratory and pilot-scale findings on PRBs for pharmaceutical removal, identifying critical knowledge gaps including long-term field validation, media regeneration, and performance under realistic wastewater matrices and outlining future research directions for scaling PRBs toward full-scale implementation. The study demonstrates that PRBs represent a viable and sustainable tertiary treatment option for reducing pharmaceutical loads in aquatic environments.