Karimi, MohsenFerreira, AlexandreRodrigues, AlírioNouar, FaridSerre, ChristianSilva, José A.C.2023-01-202023-01-202023Karimi, Mohsen; Ferreira, Alexandre; Rodrigues, Alírio; Nouar, Farid; Serre, Christian; Silva, José A.C. (2023). MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes. Industrial & Engineering Chemistry Research. ISSN 0888-5885. 62:12, p. 5216-52290888-5885http://hdl.handle.net/10198/26621The microporous bioderived Al dicarboxylate MIL-160(Al) MOF in its shaped form has been evaluated as a candidate for biogas upgrading (BU) and/or carbon capture and storage (CCS) by studying adsorption isotherms of CO2, CH4, and N2 at 313, 343, and 373 K until 8 bar. The isotherms disclosed the following loading capacities: 4.2 (CO2), 2.07 (CH4), and 0.69 (N2) mol/kg at 5.8 bar and 313 K, which fitted with the dual-site Langmuir model. The linear-driving-force coefficients (LDFs) for CO2 and CH4 calculated from uptake rate experiments are in the order of 0.021-0.096 and 0.041-0.165 s-1 at 313 K between 0.11 and 2.76 bar, respectively. The Response Surface Methodology (RSM) was also applied to maximize the selectivity for mixtures CO2/CH4 and CO2/N2 with interest for BU or CCS. Breakthrough curve experiments with mixtures CO2/CH4 and CO2/N2 at the optimum selectivity conditions were developed and simulated using ASPEN Adsorption. This work clearly demonstrates the potential of MIL-160(Al) to be used in BU and/or CCS-related applications.engMetal-organic frameworksMolecular simulationGas-adsorptionCarbon captureSeparationWaterPerformanceDesignCH4AdsorbentsSeparationjournal article10.1021/acs.iecr.2c04150