Aly, EzzeldinZafanelli, Lucas F.A.S.Henrique, AdrianoFreitas, Francisco A. da SilvaRodrigues, AlírioSilva, José A.C.2024-10-212024-10-212023Aly, Ezzeldin; Zafanelli, L.F.A.S; Freitas, Francisco; Rodrigues, Alírio E.; Silva, José A.C. (2023). Single- and multi-component fixed-bed adsorption of CO2, CH4, and N2 on ion-exchanged binder-free NaY zeolites. In 14th CHEMPOR 2023 Meeting. Bragança, Portugal.http://hdl.handle.net/10198/30458Ion-exchange was performed on bare commercial binder-free NaY zeolite with alkali (K+) and alkaline earth (Ca2+) metal cations in the range 23, 58, and 95% exchange for K+, and 56 and 71% for Ca2+, to be used as candidates regarding CO2 post-combustion capture (PCC) and biogas upgrading by adsorption processes. Adsorption equilibrium isotherms of CO2, CH4 and N2 were measured on all these cation-exchanged samples using a chromatographic technique between 308 and 348 K and pressures up to 350 kPa and modelled by the dual-site Langmuir isotherm. The CO2 adsorption capacity increases as Na+ is exchanged further by K+ and the reverse for the Ca2+ exchange. The single- and binary-component breakthrough curves were numerically simulated and accurately predicted using the Aspen Adsorption package. This work discloses the importance of ion-exchange on binder-free beads of NaY zeolite to improve its performance in PCC and biogas upgrading applicationsengPost-combustion captureNumerical simulationsIon-exchangeBinder-free faujasite zeolitesconference object