Casás, Lídia M.Orge, BeatrizFerreira, Olga2010-02-252010-02-252008Casás, Lídia M.; Orge, Beatriz; Ferreira, Olga (2008). Liquid–liquid equilibria of mixtures containing methyl acetate + methanol + hexane or heptane. Journal of Chemical & Engineering Data. ISSN 1520-5134. 53:1, p.89-931520-5134http://hdl.handle.net/10198/2163This paper reports the results of a new experimental study of liquid–liquid equilibria for the mixtures methyl acetate + methanol + hexane or heptane at atmospheric pressure and at (268.15, 278.15, 288.15, and 298.15)K. The equilibrium compositions were measured by gas chromatography from samples split isothermally into a glass-stirred device, and phase diagrams are reported at each temperature. The experimentally determined liquid-liquid equilibria were satisfactorily correlated by the NRTL and UNIQUAC equations. A comparative analysis was performed by application of UNIFAC group contribution method and its modifications to predict experimental liquid–liquid equilibria (LLE) behavior of these ternary mixtures. A poor prediction was observed from these contribution methods.engjournal article10.1021/je700397g