Please use this identifier to cite or link to this item: http://hdl.handle.net/10198/5892
Title: New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
Author: Vilas-Boas, Miguel
Freire, C.
Castro, B.
Christensen, P.A.
Hillman, A.R.
Issue Date: 1997
Publisher: A
Citation: Vilas-Boas, Miguel; Freire, C.; Castro, B.; Christensen, P.A.; Hillman, A.R. (1997) - New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer. Inorganic Chemistry. ISSN 0020-1669. 36:22, p. 4919-4929
Abstract: Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.
Peer review: yes
URI: http://hdl.handle.net/10198/5892
ISSN: 0020-1669
Appears in Collections:ARN - Artigos em Revistas Indexados ao ISI/Scopus

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