Utilize este identificador para referenciar este registo: http://hdl.handle.net/10198/5092
Título: Dynamic study of the synthesis of 1,1-dibutoxyethane in a fixed-bed adsorptive reactor
Autor: Graça, Nuno S.
Pais, L.S.
Silva, V.M.T.M.
Rodrigues, A.E.
Palavras-chave: 1,1-Dibutoxyethane
Fixed-bed adsorptive reactor
Process intensification
Data: 2011
Citação: Graça, N.S.; Pais, L.S.; Silva, V.M.T.M.; Rodrigues, A.E. (2011) - Dynamic study of the synthesis of 1,1-dibutoxyethane in a fixed-bed adsorptive reactor. Separation Science Technolology. ISSN 0149-6395. 46, p.631-640
Relatório da Série N.º: 46;
Resumo: The synthesis of 1,1-Dibutoxyethane in a fixed-bed adsorptive reactor using Amberlyst 15 was studied for the first time. The adsorption of non-reactive pairs was investigated experimentally, at 25 °C, by frontal chromatography in a fixed-bed adsorber. In order to avoid the immiscibility of the liquid phase, the liquid-liquid equilibrium for the mixture 1-butanol/water was studied. The multicomponent equilibrium adsorption data was assumed to follow the modified Langmuir type isotherm. Reaction experiments of 1,1-Dibutoxyethane production and column regeneration were performed in the fixed-bed adsorptive reactor. This work will enable further developments in chromatographic reactors aiming at the 1,1-Dibutoxyethane process intensification.
Peer review: yes
URI: http://hdl.handle.net/10198/5092
ISSN: 0149-6395
Aparece nas colecções:CIMO - Artigos em Revistas Indexados à WoS/Scopus

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