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Title: Kinetic Modeling of Non-Linear Polymerization
Authors: Costa, Mário Rui
Dias, Rolando
Keywords: Gelation
Molecular weight distribution
Non-linear polymers
Radical polymerization
Ziegler-Natta polymerization
Issue Date: 2006
Publisher: Wiley Interscience
Citation: Costa, Mário; Dias, Rolando (2006) - Kinetic modeling of non-linear polymerization. Macromolecular Symposia. ISSN 1022-1360. 243:1, p. 72-82
Abstract: Recent developments of a method based upon population balances of generating functions of polymer chain length distributions (CLD) are presented. The calculation of the CLD and how to take into account chain length dependent reactivity are discussed. Prediction of polymer properties is also possible but only easily done for the average molecular radius of gyration; some results are presented for a radical polymerization including transfer to polymer and propagation with terminal double bonds.
Peer review: yes
ISSN: 1022-1360
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Appears in Collections:DTQB - Publicações em Proceedings Indexadas ao ISI/Scopus

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