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Title: Synthesis of thienocarbazoles by reductive cyclization of 6-(2’- nitrophenyl)benzo[b]thiophenes
Author: Ferreira, Isabel C.F.R.
Queiroz, Maria João R.P.
Kirsch, Gilbert
Issue Date: 2000
Citation: Ferreira, Isabel C.F.R.; Queiroz, Maria-João R.P.; Kirsch, Gilbert (2000) – Synthesis of thienocarbazoles by reductive cyclization of 6-(2’- nitrophenyl)benzo[b]thiophenes. In XIX th European Colloquium on Heterocyclic Chemistry. Aveiro
Abstract: Thienocarbazoles are bioisosters of anti-tumoural pyridocarbazoles, ellipticine and olivacine. Methylated thienocarbazoles 1 were synthesized by reductive cyclization of 6-(2'nitrophenyl) benzo[b]thiophenes 2, using triethylphosphite. Compounds 2 were obtained by palladium-catalyzed cross-coupling between 2-bromo or iodonitrobenzenes and 6-boronic esters of methylated benzo[b]thiophenes (communication presented at this meeting).
Peer review: yes
Appears in Collections:BB - Resumos em Proceedings Não Indexados ao ISI/Scopus

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