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|Title:||Measurement and modeling of solubilities of D-glucose in water/alcohol and alcohol/alcohol systems|
|Authors:||Peres, António M.|
Macedo, Eugénia A.
|Citation:||Peres, António M.; Macedo, Eugénia A. (1997) - Measurement and modeling of solubilities of D-glucose in water/alcohol and alcohol/alcohol systems. Industrial Engineering Chemical Research. ISSN 0888-5885. 36:7, p. 2816-2820|
|Abstract:||In this work, the solubilities of D-glucose in water/methanol and ethanol/methanol mixtures are measured at 40 and 60 °C, using a simple and accurate analytical method. A modified UNIQUAC model is used for the correlation of the experimental solubility data. New UNIQUAC interaction parameters for the pairs D-glucose/alcohol, water/alcohol, and alcohol/alcohol are estimated based on the ternary solubility data presented in this work together with those available in the literature for D-glucose in water/ethanol. The solubility calculations were performed using an equation based on enthalpy of fusion data for D-glucose. The model describes satisfactorily the experimental solubility data of D-glucose in water/ethanol, water/methanol, and ethanol/methanol mixtures at both temperatures.|
|Appears in Collections:||PTV - Artigos em Revistas Indexados ao ISI/Scopus|
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