Biblioteca Digital do Instituto Politécnico de Bragança   Instituto Politécnico de Bragança

Biblioteca Digital do IPB >
Escola Superior de Tecnologia e Gestão >
Tecnologia Química e Biológica >
DTQB - Artigos em Revistas Indexados ao ISI >

Please use this identifier to cite or link to this item: http://hdl.handle.net/10198/2571

Título: Calculation of CLD using population balance equations of generating functions: linear and non-linear ideal controlled radical polymerization
Autor: Dias, Rolando
Costa, Mário Rui
Palavras-chave: Controlled radical polymerization
Cross-linking
Generating function
Molecular weight distribution
Population balances
Issue Date: 2010
Editora: WILEY-VCH
Citação: Dias; Rolando, Costa; Mário (2010) - Calculation of CLD using population balance equations of generating functions: linear and non-linear ideal controlled radical polymerization. Macromolecular Theory and Simulations. ISSN 1022-1344.
Relatório da Série N.º: 19;
Resumo: Population balance equations in terms of generating functions (GF) are used to predict chain length distributions (CLD) of linear and non-linear ideal controlled radical polymerization (CRP) systems. It is here shown that under simplified conditions analytical solutions for the CLD can be found and moreover the fundamental CLD derived by H. Tobita in 2006 is a limiting case of the more general solutions here presented. In order to deal with more complex CRP systems, solutions based upon the numerical inversion of GF are presented. These studies are also extended to the non-linear CRP of vinyl/divinyl monomers where multimodal CLDs are predicted to occur.
Descrição: Fundação para a Ciência e a Tecnologia (FCT), Ministry of Science and Technology of Portugal, European Community through FEDER, Project PTDC/EQU-EQU/098150/2008 (COMPETE-QCA III), Marie Curie Initial Training Network Nanopoly (ITN-GA-2009-238700)
URI: http://hdl.handle.net/10198/2571
ISSN: 1022-1344
Versão do Editor: http://onlinelibrary.wiley.com/doi/10.1002/mats.201000008/abstract
Appears in Collections:DTQB - Artigos em Revistas Indexados ao ISI

Files in This Item:

There are no files associated with this item.


Statistics
FacebookTwitterDeliciousLinkedInDiggGoogle BookmarksMySpaceOrkut
Formato BibTex mendeley Endnote Logotipo do DeGóis 

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 


  © Instituto Politécnico de Bragança - Biblioteca Digital - Feedback - Statistics
  Estamos no RCAAP Governo Português separator Ministério da Educação e Ciência   Fundação para a Ciência e a Tecnologia

Financiado por:

POS_C UE