Biblioteca Digital do Instituto Politécnico de Bragança   Instituto Politécnico de Bragança

Biblioteca Digital do IPB >
Escola Superior de Tecnologia e Gestão >
Tecnologia Química e Biológica >
DTQB - Artigos em Revistas Indexados ao ISI/Scopus >

Please use this identifier to cite or link to this item:

Título: Carbon supported iridium catalysts in the catalytic wet air oxidation of carboxylic acids: kinetics and mechanistic interpretation
Autor: Gomes, Helder
Figueiredo, José
Faria, Joaquim
Serp, Philippe
Kalck, Philippe
Palavras-chave: Catalytic wet air oxidation
Carbon-supported iridium catalysts
Incipient wetness impregnation
Organometallic chemical vapor deposition
Heterogeneous-catalyzed free-radical mechanism
Issue Date: 2002
Editora: Elsevier
Citação: Gomes, Helder; Figueiredo, José; Faria, Joaquim; Serp, Philippe; Kalck, Philippe (2002) - Carbon supported iridium catalysts in the catalytic wet air oxidation of carboxylic acids: kinetics and mechanistic interpretation. Journal of Molecular Catalysis A: Chemical. ISSN 1381-1169. 182:1 Special Issue: SI, p. 47-60
Resumo: Carbon-supported iridium catalysts were prepared by different incipient wetness impregnation methods and by organometallic chemical vapor deposition. The catalysts were characterized by N2 adsorption, TPD, SEM and H2 chemisorption measurements. The results obtained indicate a clear dependency of the metal-phase dispersion on the pre-treatment of the carbon support and the impregnation method. Their activity for catalytic wet air oxidation of butyric and iso-butyric acid aqueous solutions was investigated in a stirred reactor at 473K and 0.69MPa of oxygen partial pressure. The conversions obtained after 2 h were 43 and 52%,with respect to each carboxylic acid, when the most active catalysts were used. The measured conversions and initial reaction rates correlate well with the exposed metal area. A rate equation was determined from measurements of the initial reaction rates at different oxygen partial pressures, temperatures and catalyst mass loads. The results were modeled considering a heterogeneously catalyzed free-radical mechanism.
ISSN: 1381-1169
Versão do Editor:
Appears in Collections:DTQB - Artigos em Revistas Indexados ao ISI/Scopus

Files in This Item:

File Description SizeFormat
JMolCat-182_183-47-2002.pdf316,23 kBAdobe PDFView/Open
Restrict Access. You can request a copy!
JMolCat-182_183-47-2002 - resumo.pdf27,02 kBAdobe PDFView/Open

Please give feedback about this item
FacebookTwitterDeliciousLinkedInDiggGoogle BookmarksMySpace
Formato BibTex MendeleyEndnote Logotipo do DeGóis 

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.


© Instituto Politécnico de Bragança - Biblioteca Digital - Feedback - Statistics
Promotores do RCAAP   Financiadores do RCAAP

Fundação para a Ciência e a Tecnologia Universidade do Minho   Governo Português Ministério da Educação e Ciência PO Sociedade do Conhecimento (POSC) Portal oficial da União Europeia