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Palladium-catalyzed amination and cyclization to heteroannellated indoles and carbazoles

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Abstract(s)

New ortho-bromodiarylamines in the benzo[b]thiophene series were prepared by palladium-catalyzed amination, either in the benzene or in the thiophene ring. These were submitted to palladium-catalyzed cyclization, under different required conditions, to give several differently substituted thieno[3,2-c] or [2,3-b]carbazoles and indolo[3,2-b]benzo[b]thiophenes. This constitutes a novel synthetic route to both tetracyclic systems

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Palladium Amination Ortho-bromodiarylamines Cyclization

Citation

Tetrahedron. ISSN 0040-4020. 59:21 (2003) p. 3737-3743

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