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Resumo(s)
Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.
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Citação
Vilas-Boas, Miguel; Freire, C.; Castro, B.; Christensen, P.A.; Hillman, A.R. (1997). New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer. Inorganic Chemistry. ISSN 0020-1669. 36:22, p. 4919-4929
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