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Synthesis of diarylamines in the benzo[b]thiophene series bearing electron donating or withdrawing groups

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The synthesis of diarylamines has attracted a great deal of interest due to their importance in diverse fields as natural biological active products and analogues, photography and materials science. Herein we report the synthesis of diarylamines 1 bearing electron donating or withdrawing groups by palladium catalyzed amination, in good yields (50%-quantitative yield) using two different bases and choosing the right components.

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Ferreira, Isabel C.F.R.; Queiroz, Maria João R.P.; Kirsch, Gilbert (2002). Synthesis of diarylamines in the benzo[b]thiophene series bearing electron donating or withdrawing groups. In XXth European Colloqium on Heterocyclic Chemistry. Estocolmo

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