Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework

Bárcia, Patrick da Silva; Zapata, Fátima; Silva, José A.C.; Rodrigues, Alírio; Chen, Banglin

http://hdl.handle.net/10198/3306

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Authors

Bárcia, Patrick da Silva

Abstract(s)

A three-dimensional microporous metal-organic framework Zn(BDC)(Dabco)(0.5) (BDC = 1,4-benzenedicarboxylate, Dabco = 1,4-diazabicyclo [2,2,2]octane), having two types of intersecting pores to encapsulate linear hexane and to block branched hexanes, and thus exhibiting highly selective sorption with respect to n-hexane, has been successfully applied to the kinetic separation of hexane isomers by fixed-bed adsorption.

Keywords

Adsorption

URI

http://hdl.handle.net/10198/3306

Citation

Barcia, Patrick; Zapata, Fátima; Silva, Jose A.C; Rodrigues, Alirio; Chen, Banglin (2007). Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework. JOURNAL OF PHYSICAL CHEMISTRY B. ISSN: 1520-6106. 111:22, p. 6101- 6103