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Abstract(s)
In this work, partial molar volumes of glycine and L-alanine in aqueous solutions of magnesium sulphate at (0.0, 0.1, 0.3, 0.7 and 1.0) molal were obtained between 278.15 K and 308.15 K.
Additionally, partial molar volumes of transfer at infinite dilution and hydration numbers were calculated. In general, transfer volumes are higher for glycine then L-alanine. From the transfer volumes, it can be concluded that the predominant interactions are pairwise between ions and zwitterionic centers of the amino acids. On the other hand, hydration numbers are higher for L-alanine than glycine. Dehydration of the studied amino acids is observed, rising either temperature or salt molality.
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Citation
Mota, Carolina C.; Ferreira, Olga; Pinho, Simão (2014). Partial molar volumes of glycine and L-Alanine in aqueous MgSO4 solutions between 278.15 and 308.15 K. In 12th International Chemical and Biological Engineering Conference. FEUP, Porto, Portugal